This publication deals with the study of the mechanical properties of injection-molded polypropylene parts depending on the process parameters and the distance from the gate location in which the mechanical properties were investigated. Due to the fact that the mechanical properties of injection-molded parts are not the same at all locations, this research was designed to investigate the inhomogeneity of the properties of injection-molded parts along the length of the product. The inhomogeneity is affected by various influences, including distance from the sprue mouth, melt and mold temperature, injection pressure, crystal structure, and others. It was demonstrated that mechanical properties are not uniform over the entire injected product. Contrary to popular belief, mechanical properties can vary along the flow length due to uneven cooling and process parameters. Injection pressure and mold temperature significantly affect the mechanical properties of the injection-molded parts. The limiting injection pressure is 40 MPa and the mold temperature is 40 °C. The difference in individual spots in an injected article was up to 37%. Changes in mechanical properties are closely related to changes in morphology (crystallinity measured by DSC) caused by different injection molding process parameters. As is evident from the aforementioned results, the possible benefits of this work for injection molding of polymer products are apparent. Suitably chosen gate location, surface of the cavity, and process parameters can ensure targeted improvement of mechanical properties in stressed parts of a product.

This study describes the effect of electron radiation on the macro- and micro-mechanical and tribological properties of composite polypropylene filled with 25% glass fiber. Micro-mechanical and tribological properties were investigated both on the sample surface and at various depths below the surface. Polypropylene was irradiated with radiation doses of 15, 33, 45, 66 and 99 kGy. As the results show, electron radiation has an influence on the change in PP’s structure, in which due to the electron radiation, a crosslinked phase and an increase in crystallinity are formed. These changes in morphology are reflected in an enhancement of micro-mechanical and tribological properties both at the surface and in deeper layers below the surface. More crosslinking and recrystallization occur across the sample’s cross-section up to a depth of 2 mm, where greater micro-mechanical and tribological properties are also measured. The difference between the surface and the center of the material can be up to 32%. The optimum radiation dose appears to be 45 kGy, where the maximum crosslinking, highest crystallinity and best micro-mechanical and tribological properties are found. The difference between non-irradiated and irradiated filled PP is 52% in indentation hardness. In terms of macro-mechanical properties, the tensile modulus increased by 44% (45 kGy). This translates into higher surface wear resistance and the overall stiffness of the part. Higher doses of radiation cause the beginning of degradation processes, which are manifested by a decrease in the degree of embedding, crystallinity and thus micro-mechanical and tribological properties.

This study examines the tribological and micro-mechanical behavior of high-density polyethylene (HDPE), which has been advanced to the class of advanced polymers through electron beam irradiation (irradiation dose of 33 kGy to 198 kGy). The tribological and mechanical behaviors were analyzed at the surface and at various depths beneath the surface to verify the extent of radiation effects across the entire cross-section of the specimen. Changes in tribological and mechanical behavior are closely related to changes in the structure of the material, mainly changes in crystallinity. As this study shows, 99 kGy appears to be the ideal radiation dose in terms of the properties examined. An increase in absorbed radiation dose leads to a deterioration of tribological and mechanical performance, which correlates with material degradation and a concomitant reduction in crystallinity. The improvement in the properties examined between unirradiated and irradiated HDPE at a dose of 99 kGy is 18% for mechanical behaviors and 8% for tribological behaviors on the surface of the sample. A maximum deviation of 39% was identified between the surface and the center of the material. There was also a change in crystallinity of up to 12%. These modifications result in enhanced surface wear resistance and increased overall stiffness, effectively shifting commodity-grade HDPE toward the performance domain of advanced polymers with only minimal cost implications.