Polymers and plastics are crucial materials in many sectors of our economy, due to their numerous advantages. They also have some disadvantages, among the most important are problems with the recycling and disposal of used plastics. The recovery of waste plastics is increasing every year, but over 27% of plastics are landfilled. The rest is recycled, where, unfortunately, incineration is still the most common management method. From an economic perspective, waste management methods that lead to added-value products are most preferred—as in the case of material and chemical recycling. Since chemical recycling can be used for difficult wastes (poorly selected, contaminated), it seems to be the most effective way of managing these materials. Moreover, as a result this of kind of recycling, it is possible to obtain commercially valuable products, such as fractions for fuel composition and monomers for the reproduction of polymers. This review focuses on various liquefaction technologies as a prospective recycling method for three types of plastic waste: PE, PP and PS.

It is known that biogas without prior purification to biomethane is a commonly used fuel only for the stationary internal combustion engines but not for vehicle engines. The current study evaluates the use of biogas without its prior upgrading to biomethane as fuel for tractor engines. The following tests were carried out: biochemical methane potential tests, dynamometer engine tests, and field tests with the use of a tractor. The average methane content in biogas obtained from vegetable wastes exceeded 60%. The tests performed on the engine dynamometer showed that the engine powered by dual fuel worked stably when diesel was replaced by 40% biogas (containing 50% of CO₂) or 30% methane. Dual fuel supplying of the engine caused an increase in the concentration of hydrocarbons and carbon monoxide in the exhaust gases and a decrease or no effect in the concentration of particulate matter and nitrogen oxides. It did not significantly affect the dynamics of the vehicle and its useful properties. Biogas that contains a maximum of 50% CO₂ and from which H₂S, moisture, and siloxanes have been largely removed, is suitable as a fuel for tractors. Such biogas can be obtained in biogas plants from different substrates, e.g., vegetable or agriculture wastes as well as biodegradable municipal wastes.

This research paper studied the environmental impact of using methane fuels for supplying internal combustion engines. Methane fuel types and the methods of their use in internal combustion engines were systematized. The knowledge regarding the environmental impact of using methane fuels for supplying internal combustion engines was analyzed. The authors studied the properties of various internal combustion engines used for different applications (specialized engines of power generators—Liebherr G9512 and MAN E3262 LE212, powered by biogas, engine for road and off-road vehicles—Cummins 6C8.3, in self-ignition, original version powered by diesel fuel, and its modified version—a spark-ignition engine powered by methane fuel) under various operating conditions in approval tests. The sensitivity of the engine properties, especially pollutant emissions, to its operating states were studied. In the case of a Cummins 6C8.3 modified engine, a significant reduction in the pollutant emission owing to the use of methane fuel, relative to the original self-ignition engine, was found. The emission of carbon oxide decreased by approximately 30%, hydrocarbons by approximately 70% and nitrogen oxide by approximately 50%, as well as a particulate matter emission was also eliminated. Specific brake emission of carbon oxide is the most sensitive to the operating states of the engine: 0.324 for a self-ignition engine and 0.264 for a spark-ignition engine, with the least sensitive being specific brake emission of nitrogen oxide: 0.121 for a self-ignition engine and 0.097 for a spark-ignition engine. The specific brake emission of carbon monoxide and hydrocarbons for stationary engines was higher in comparison with both versions of Cummins 6C8.3 engine. However, the emission of nitrogen oxide for stationary engines was lower than for Cummins engines.

This publication presents the technologies of enzymatic biodiesel production in comparison to the conventional methods using acid and base catalysts. Transesterification with conventional catalysts has some disadvantages, and for this reason, alternative methods of biodiesel production have been investigated. These solutions include the replacement of chemical catalysts with biological ones, which show substrate specificity in relation to fats. Replacing chemical with biological catalysts causes elimination of some disadvantages of chemical processes, for instance: high temperatures of reaction, problematic process of glycerol purification, higher alcohol-to-oil molar ratios, and soap formation. Moreover, it causes operational cost reduction and has a positive environmental impact. This is due to the lower temperature of the process, which in turn translates into lower cost of equipment and lower GHG emissions associated with the need to provide less heat to the process. The increase of biofuels’ demand has led to the technology of enzymatic biodiesel production being constantly being developed. This research mainly focuses on the possibility of obtaining cheaper and more effective biocatalysts, as well as increasing the durability of enzyme immobilization on different materials.

The paper presents the results of research on the use of flake graphene as an additive to plastic grease in order to improve its tribological properties. The influence of concentration (0.25–5.00 wt.%) and the form of graphene (graphene oxide, reduced graphene oxide) on selected properties of the base grease were investigated. It has been found that the addition of graphene flakes improves the anti-wear properties of the lubricant. The greatest improvement in the properties of the lubricant was achieved by using graphene at a concentration of 4.00 wt.%; the reduction in the average diameter of the wear scar was almost 70% for GO and RGO, compared to the base lubricant without the addition of graphene.

Life cycle analysis allows for the assessment of the qualitative and quantitative relationship between selected areas of human activity and the consequences for the environment. One of the important areas is the production of electricity and heat, for which the main raw material in Poland is hard coal. An alternative may be to use biogas as a fuel for energy purposes. This article presents the assessment of environmental hazards caused by the production of energy from biogas. The analysis took into account the change of the substrate from maize silage, commonly used in Polish biogas plants, to waste from the domestic agri-food industry. The evaluation covered the acquisition of substrates, their transport to a biogas plant, generation of electricity from biogas, and management of the generated by-products. The analysis was done in terms of both the impact and sensitivity categories. It was found that the emission of pollutants related to the acquisition of the substrate plays a key role and the use of waste for the production of biogas used for energy production brings environmental benefits. The analysis has shown that replacing coal with biogas, regardless of the raw materials used in its production, results in a positive environmental effect, especially in the areas of human health and resources categories. The positive environmental effect of the production of electricity from biogas can be enhanced by switching raw materials from purpose-grown crops to waste from the agri-food industry and agriculture. An important factor influencing the environmental impact is the degree of heat utilization (the greater the percentage of heat utilization, the greater the environmental benefits) and management of all by-products.