We report the synthesis of new laterally alkyl substituted high birefringent quaterphenyl and phenylethynyltolane liquid crystals with isothiocyanate terminal group. The thermal and optical properties such as birefringence are measured and discussed based on their molecular structures. The compounds exhibit birefringence (Δn) in the range of 0.44–0.63, and are expected to be appropriate components of high birefringent nematic mixtures for various applications.
7 January 2019 in Beilstein Journal of Nanotechnology
We report a threshold voltage decrease in a nematic liquid crystal compound, 4-cyano-4′-pentylbiphenyl (5CB), doped with graphene oxide (GO) flakes at a concentration of 0.05–0.3 wt %. The threshold voltage decrease was observed at the same concentration in electro-optic and dielectric spectroscopy measurements. The effect is related to the disrupted planar alignment due to the strong π–π stacking between the 5CB’s benzene rings and the graphene oxide’s structure. Additionally, we present the GO concentration dependence on the isotropic–nematic phase transition temperature, electric anisotropy, splay elastic constant, switch-on time, and switch-off time. The shape and dimensions of the GO flakes were studied using atomic force microscopy (AFM) and scanning electron microscopy (SEM). The influence of the GO concentration on the physical properties and switching process in the presence of the electric field was discussed.
Since rigid polyurethane (PU) foams are one of the most effective thermal insulation materials with widespread application, it is an urgent requirement to improve its fire retardancy and reduce the smoke emission. The current work assessed the fire behavior of PU foam with non-halogen fire retardants system, containing histidine (H) and modified graphene oxide (GOA). For investigated system, three loadings (10, 20, and 30 wt.%) were used. The Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), thermogravimetric analysis, cone calorimetry (CC) and smoke density chamber tests as well as pre- and post-burning morphological evaluation using scanning electron microscope (SEM) were performed. Moreover, TGA combined with FT-IR was conducted to determine the substances, which could be evolved during the thermal decomposition of the PU with fire retardant system. The results indicated a reduction in heat release rate (HRR), maximum average rate of heat emission (MAHRE), the total heat release (THR) as well as the total smoke release (TSR), and maximum specific optical density (Dsmax) compared to the polyurethane with commercial fire retardant, namely ammonium polyphosphate (APP). A significantly improvement, especially in smoke suppression, suggested that HGOA system may be a candidate as a fire retardant to reduce the flammability of PU foams.
This article investigates the possibilities of gas detection using a tapered optical fiber coated with a graphene oxide layer. Measurement is based on changes in light beam propagation depending on the process of gas absorption to the graphene oxide layer. In this paper, we investigated the light change in a double-clad tapered optical fiber in a wide optical range. We present a special platform constructed for the deposition of additional functional materials that enable the preparation of the sensor module. Our results present differences in light transmission for three different kinds of gasses pure nitrogen, pure hydrogen, and a mixture of propane–butane. Measurements were provided in a wide range of 500 nm–1800 nm to find the most sensitive ages for which we are able to detect mentioned absorption and their interaction with light. Obtained results for pure gasses for which the refractive indices are similar to the air show the greatest changes for the visible range 750 nm–850 nm, and for propane–butane, changes are much visible in the whole investigated range.
Additive manufacturing (AM) has seen remarkable development in recent years due to relatively high efficiency of the process. Cold spraying (CS) is a particular method of AM, in which titanium and titanium alloy powders are used. CS is a very competitive technology enabling the deposition of coatings, repairing machine parts, and manufacturing new components. For specific applications, the surface of cold-sprayed materials may require further processing. This paper reports an attempt to employ laser surface treatment (LST) of cold-sprayed coatings on an aluminium alloy substrate. The influence of laser beam interaction time on the coatings’ properties was analysed. The microstructure was investigated and observed employing scanning electron microscopy (SEM). To evaluate residual stress after CS and LST, the sin2ψ technique was used. Investigations were also performed on Vickers hardness, contact angle, and surface roughness. Significant changes in the surface morphology of the coatings and elevated residual stress levels dependent on the laser beam interaction time were observed. Increased Vickers hardness was recorded for titanium alloy Ti6Al4V. LST also led to increased surface hydrophilicity of the modified materials Ti and Ti6Al4V.
Optical properties of a nematic liquid crystal with small refractive index and small birefringence were studied. The ordinary and extraordinary refractive indices and birefringence were measured as functions of temperature by using an Abbe refractometer and wedge nematic cells. From values of these indices the nematic orientational order parameter was calculated by using several methods and corresponding mathematical models. Kuczyński et al. method was found to be suitable for determining the order parameter also for materials featuring small ordinary refractive index, with unknown density.