Self-cleaning surfaces may have wide applications such as microfluidic devices, lab-on-a-chip, sensors, microreactors, air purification, and antimicrobial fields. In this article, by using a combination of femtosecond (fs) laser irradiation and fluorination technique, self-cleaning stainless steel surfaces with unique antifouling property were obtained. New insight is developed through a detailed analysis of the antifouling behavior of the self-cleaning surfaces. The surface free energy and its polar and disperse components were calculated by using the Owens–Wendt-–Rabel–Kaelble (OWRK) method. X-ray photoelectron spectroscopy was employed to analyse the surface elemental compositions and functional groups. The antifouling property of the surface was recorded by using a high speed camera. Water sliding angles (SAs) were reduced by fluorination treatment, resulting in low adhesive superhydrophobic surfaces with the self-cleaning property. The influences of micro/nanostructures, fluorination, and their combination on the surface free energy were investigated. The interaction process between water droplets and pollutants (inorganic and organic particles) on the treated surface was explored. The antifouling property of an optimized specimen (CA = 162° and SA = 1°) was tested and compared with the untreated sample.
The RDX single crystals are ignited by ultraviolet laser (355 nm, 6.4 ns) pulses. The laser-induced damage morphology consisted of two distinct regions: a core region of layered fracture and a peripheral region of stripped material surrounding the core. As laser fluence increases, the area of the whole crack region increases all the way, while both the area and depth of the core region increase firstly and then stay stable over the laser fluence of 12 J/cm2. The experimental details indicate the dynamics during laser ignition process. Plasma fireball of high temperature and pressure occurs firstly, followed by the micro-explosions on the (210) surface and finally shock waves propagate through the materials to further strip materials outside and yield in-depth cracks in larger surrounding region. The plasma fireball evolves from isotropic to anisotropic under higher laser fluence resulting in the damage expansion only in lateral direction while maintaining the fixed depth. The primary insights into the interaction dynamics between laser and energetic materials can help developing the superior laser ignition technique.
Repairing initial slight damage site into stable structures by engineering techniques is the leading strategy to mitigate the damage growth on large-size components used in laser-driven fusion facilities. For KH2PO4crystals, serving as frequency converter and optoelectronic switch-Pockels cell, micro-milling has been proven the most promising method to fabricate these stable structures. However, tool marks inside repairing pit would be unavoidably introduced due to the wearing of milling cutter in actual repairing process. Here we quantitatively investigate the effect of tool marks on repairing quality of damaged crystal components by simulating its induced light intensification and testing the laser-induced damage threshold. We found that due to the formation of focusing hot spots and interference ripples, the light intensity is strongly enhanced with the presence of tool marks, especially for those on rear surfaces. Besides, the negative effect of tool marks is mark density dependent and multiple tool marks would aggravate the light intensification. Laser damage tests verified the role of tool marks as weak points, reducing the repairing quality. This work offers new criterion to comprehensively evaluate the quality of repaired optical surfaces to alleviate the bottleneck issue of low laser damage threshold for optical components in laser-driven fusion facilities.
A simple and convenient means of fabricating concave microlens arrays direct on silica glass by using the local fictive temperature modification of fused silica is presented. This method is based on the fact that an increased fictive temperature results in a much higher HF acid etching rate of fused silica. Combining the abrupt local fictive temperature enhancement by the laser pulse and the subsequent etching by the HF acid solution, concave microlens arrays with high fill factors, excellent smoothness, and optical performance are generated on fused silica.