Lignocellulosic biomass, derived from plant materials, represents a renewable alternative to fossil fuels and plays a crucial role in advancing environmental sustainability. This systematic review investigates recent developments in the conversion of lignocellulosic biomass into biofuels, with a focus on pre-treatment technologies that enhance enzymatic hydrolysis, a critical step in efficient biofuel production. This review addresses two primary questions: (1) What are the most effective pre-treatment methods for enhancing enzymatic hydrolysis in lignocellulosic biomass conversion? (2) How do these pre-treatment methods compare in terms of efficiency, environmental impact, and economic feasibility? Consequently, studies were selected based on inclusion criteria that focus on research investigating these pre-treatment methods and their comparative performance. A structured search of original studies was applied across databases such as Crossref, Google Scholar, Scopus, PubMed, and Semantic Scholar, resulting in the inclusion of 17 peer-reviewed articles published between 2019 and 2024. The findings highlight effective pre-treatment methods that significantly improve enzymatic accessibility and bioethanol yields. However, ongoing challenges such as feedstock variability, process efficiency, and cost-effectiveness remain. These results highlight the need for further research and development to optimize conversion technologies and identify new areas for exploration.

The growing global demand for clean energy and sustainability has increased interest in lignocellulosic biomass as a viable alternative to conventional fossil fuels. Among the various biomass resources, sugarcane bagasse, an abundant agro-industrial by-product, has emerged as a promising feedstock to produce renewable fuels and value-added chemicals. Its high carbohydrate content offers significant potential for bioconversion. However, its complex and recalcitrant lignocellulosic matrix presents significant challenges that necessitate advanced pretreatment techniques to improve enzymatic digestibility and fermentation efficiency. This review consolidates recent developments in the valorization of sugarcane bagasse focusing on innovative pretreatment and fermentation strategies for sustainable bioethanol production. It emphasizes the synergistic benefits of integrating various pretreatment and fermentation methods to improve bioethanol yields, reduce processing costs and enhance overall process sustainability. This review further explores recent technological advancements, the impact of fermentation inhibitor, and emerging strategies to overcome these challenges through microbial strains and innovative fermentation methods. Additionally, it highlights the multi-faceted advantages of bagasse valorization, including waste minimization, renewable energy production and the promotion of sustainable agricultural practices. By evaluating the current state of research and outlining future perspectives, this paper serves as a comprehensive guide to advancing the valorization of sugarcane bagasse in the transition towards a low-carbon economy. The novelty of this review lies in its holistic integration of technological, economic, and policy perspectives, uniquely addressing the scalability of integrated pretreatment and fermentation processes for sugarcane bagasse, and outlining practical pathways for their translation from laboratory to sustainable industrial biorefineries within the circular bioeconomy framework.

The present study indicates that solid acid catalysis of crude tall oil (CTO) over a WO₃/ZrO₂ catalyst is effective in converting the CTO fatty acids components into biodiesel in high yield. Preparation of the catalyst by an impregnation method was selected and WO₃ activity was best at a loading mass fraction of 5% to ZrO₂ support and activation at 500°C for five hours under air at atmospheric pressure. Optimal reaction conditions were reaction temperature at 250°C; methanol to CTO molar ratio at 10; reaction time four hours, catalyst mass fraction of 3%; and stirring intensity at 625 rpm. The conversion at optimal reaction conditions was 70%. The catalyst was highly active at temperatures higher than 200°C. The biodiesel produced met some, but not all, the diesel quality parameters stipulated by standard specifications such as ASTM D6751 and EN14214.

Lignin, the most abundant renewable source of aromatic compounds, plays a pivotal role in advancing sustainable biorefineries and reducing dependence on fossil resources. Recent progress in integrated lignin valorization pathways has unlocked opportunities to convert this complex biopolymer into high-value chemicals, materials, and energy carriers, despite its structural heterogeneity and recalcitrance posing major challenges. This review highlights the significant advancements in depolymerization strategies, including catalytic, oxidative, and biological approaches, which are reinforced by innovations in catalyst design and reaction engineering that enhance selectivity and efficiency. It also discusses emerging technologies, such as hybrid chemo-enzymatic systems, solvent fractionation, and continuous-flow reactors, for their potential to improve scalability and sustainability. Furthermore, this review examines the integration of lignin valorization with upstream pretreatment and downstream recovery, emphasizing process intensification, co-product synergy, and techno-economic optimization to achieve commercial viability. Despite these developments, critical gaps remain in understanding the molecular complexity of lignin, developing universally applicable catalytic systems, and optimizing economic and environmental performance. To guide future research, it poses two key questions: how to design catalysts for selective depolymerization across diverse lignin sources, and how to configure biorefineries for maximum lignin utilization while ensuring sustainability? Addressing these challenges will be essential for lignin’s role in next-generation biorefineries and a circular bioeconomy.

The performance of IrO2/Ta2O5 coated titanium anodes in concentrated chromium VI solutions were evaluated by accelerated life tests, cyclic voltammetry and chronoamperometry techniques. Experimental results show that the anodes had a service life of up to 1059 hours under a current density of 1.2 Acm-2, which is four times the normal operating level. Chronoamperometrical tests performed at selected intervals during the accelerated life tests show that the electroactivity of the coating slowly decreases at the beginning, maintains a roughly stable condition for an intermediate period and then falls of sharply at the end. Additional analyses by SEM and EDS before and after accelerated life tests suggest that deactivation of the coating takes place by chemical/electrochemical corrosion followed by passivation of the titanium substrate.