Ternary choline chloride-based deep eutectic solvents (TDESs) exhibit unique physicochemical properties, including lower viscosities, lower melting points, higher thermal stabilities, and enhanced solvations compared to binary deep eutectic solvents (BDESs). Although BDESs have been widely studied, the addition of a third component in TDESs offers opportunities to further optimize their performance. This review aims to evaluate the physicochemical properties of TDESs and highlight their potential applications in sustainable industrial processes compared to BDESs. A comprehensive analysis of the existing literature was conducted, focusing on TDES properties, such as phase behavior, density, viscosity, pH, conductivity, and the effect of water, along with their applications in various fields. TDESs demonstrated superior physicochemical characteristics compared to BDESs, including improved solvation and thermal stability. Their applications in biomass conversion, CO₂ capture, heavy oil upgrading, refrigeration gases, and as solvents/catalysts in organic reactions show significant promise for enhancing process efficiency and sustainability. Despite their advantages, TDESs face challenges including limited predictive models, potential instability under certain conditions, and scalability hurdles. Overall, TDESs offer significant potential for advancing sustainable and efficient chemical processes for industrial applications.

Lignocellulosic biomass, derived from plant materials, represents a renewable alternative to fossil fuels and plays a crucial role in advancing environmental sustainability. This systematic review investigates recent developments in the conversion of lignocellulosic biomass into biofuels, with a focus on pre-treatment technologies that enhance enzymatic hydrolysis, a critical step in efficient biofuel production. This review addresses two primary questions: (1) What are the most effective pre-treatment methods for enhancing enzymatic hydrolysis in lignocellulosic biomass conversion? (2) How do these pre-treatment methods compare in terms of efficiency, environmental impact, and economic feasibility? Consequently, studies were selected based on inclusion criteria that focus on research investigating these pre-treatment methods and their comparative performance. A structured search of original studies was applied across databases such as Crossref, Google Scholar, Scopus, PubMed, and Semantic Scholar, resulting in the inclusion of 17 peer-reviewed articles published between 2019 and 2024. The findings highlight effective pre-treatment methods that significantly improve enzymatic accessibility and bioethanol yields. However, ongoing challenges such as feedstock variability, process efficiency, and cost-effectiveness remain. These results highlight the need for further research and development to optimize conversion technologies and identify new areas for exploration.

The growing global demand for clean energy and sustainability has increased interest in lignocellulosic biomass as a viable alternative to conventional fossil fuels. Among the various biomass resources, sugarcane bagasse, an abundant agro-industrial by-product, has emerged as a promising feedstock to produce renewable fuels and value-added chemicals. Its high carbohydrate content offers significant potential for bioconversion. However, its complex and recalcitrant lignocellulosic matrix presents significant challenges that necessitate advanced pretreatment techniques to improve enzymatic digestibility and fermentation efficiency. This review consolidates recent developments in the valorization of sugarcane bagasse focusing on innovative pretreatment and fermentation strategies for sustainable bioethanol production. It emphasizes the synergistic benefits of integrating various pretreatment and fermentation methods to improve bioethanol yields, reduce processing costs and enhance overall process sustainability. This review further explores recent technological advancements, the impact of fermentation inhibitor, and emerging strategies to overcome these challenges through microbial strains and innovative fermentation methods. Additionally, it highlights the multi-faceted advantages of bagasse valorization, including waste minimization, renewable energy production and the promotion of sustainable agricultural practices. By evaluating the current state of research and outlining future perspectives, this paper serves as a comprehensive guide to advancing the valorization of sugarcane bagasse in the transition towards a low-carbon economy. The novelty of this review lies in its holistic integration of technological, economic, and policy perspectives, uniquely addressing the scalability of integrated pretreatment and fermentation processes for sugarcane bagasse, and outlining practical pathways for their translation from laboratory to sustainable industrial biorefineries within the circular bioeconomy framework.