Recent advancements in ultraviolet (UV) photodetection technology have driven intensive research on zinc oxide (ZnO) nanomaterials due to their exceptional optoelectronic properties. This review systematically examines the fundamental detection mechanisms in ZnO-based UV photodetectors (UVPDs), including photoconductivity effects, the threshold dimension phenomenon and light-modulated interface barriers. Based on these mechanisms, a large surface barrier due to surface-adsorbed O₂ is generally constructed to achieve a high sensitivity. However, this improvement is obtained with a decrease in response speed due to the slow desorption and re-adsorption processes of surface O₂ during UV light detection. Various improvement strategies have been proposed to overcome this drawback and keep the high sensitivity, including ZnO–organic semiconductor interfacing, defect engineering and doping, surface modification, heterojunction and the Schottky barrier. The general idea is to modify the adsorption state of O₂ or replace the adsorbed O₂ with another material to build a light-regulated surface or an interface barrier, as surveyed in the third section. The critical trade-off between sensitivity and response speed is also addressed. Finally, after a summary of these mechanisms and the improvement methods, this review is concluded with an outlook on the future development of ZnO nanomaterial UVPDs.

Two-dimensional MoS₂ attracts much attention because of its potential application in electronic and optoelectronic devices at present. However, the preparation of large and uniform single crystal MoS₂ nanosheets is still a challenge, which restricts its further application. Herein, monolayer single crystal MoS₂ nanosheets with large and uniform grain size have been synthesized by chemical vapor deposition using a double-tube system. Within the main growth area, the grain size reaches 146 μm on the substrate of SiO₂/Si, and the portion of MoS₂ nanosheets with grain size between 50 μm and 100 μm is up to 78%. Meanwhile, the grain size keeps constant in the direction perpendicular to the tubes and changes slightly in the parallel direction. This is attributed to the concentration distribution of intermediate product MoO_3−x in the one-side sealed inner tube set in a quartz tube, i.e., the double-tube system, which provides a way to the controllable and uniform synthesis of large monolayer single crystal MoS₂ nanosheets.