We present high-angular resolution observations, conducted with the Atacama Large Millimeter/Submillimeter Array (ALMA) in Band 6, of high-excitation molecular lines of ${\mathrm{CH}}_3\mathrm{CN}$, CH₃OH, and the H29$\alpha$ radio recombination line, towards the G333.6-0.2 ultracompact (UC) H ii region. Our observations reveal three hot molecular cores: A, B, and C, where emission is detected in ten components of the $J=14\to 13$ rotational ladder of ${\mathrm{CH}}_3\mathrm{CN}$ and in the CH₃OH $J=5_{1,4}\to 4_{1,3}$ transition. Rotational diagram analysis of ${\mathrm{CH}}_3\mathrm{CN}$ reveals excitation temperatures ranging from 380 to 430 K. First-order moment maps of ${\mathrm{CH}}_3\mathrm{CN}$ and CH₃OH reveal distinct velocity gradients in all cores, suggesting rotating structures, with core A also showing evidence of expansion motions. The H29$\alpha$ recombination line shows a linewidth of $30.2\pm 0.12$ km s⁻¹, dominated by dynamical and thermal broadening, indicative of large-scale motions in ionized gas. Analysis of the ionized gas properties yields an electron density of $(4.8\pm 0.4)\times {10}^5$ cm⁻³, an emission measure of $(1.23\pm 0.06)\times {10}^9$ pc cm⁻⁶, and a Lyman continuum photon flux consistent with an O5–O6 V (Zero-Age Main Sequence; ZAMS) star. Our results suggest that G333.6-0.2 is in an intermediate evolutionary stage between hypercompact (HC) and ultracompact (UC) H ii regions, hosting active high-mass star formation with rotating hot cores and ionized gas dynamics.

We present high–angular resolution 1.3 mm continuum and molecular line observations toward the highmass star-forming region G350.29+0.12, using CH₃CN and CH₃¹³CN rotational transitions. The continuum emission resolves two main cores: a bright, compact northern core G350.29+0.12 A and a weaker southern core G350.29+0.12 B. Core A exhibits six compact substructures embedded within more extended emission. M K-components of the CH3CN J = 14→13 and CH3 13CN J = 14→13 transitions are detected, with the emission arising primarily from core A. The CH3CN moment 0 maps show that the integrated intensities peak at the main continuum position, indicating that the molecular emission traces warm and dense gas. The moment 1 maps reveal a pronounced velocity gradient of ∼2 km s-1 across core A, oriented from northwest to southeast, while the moment 2 maps show K-dependent variations in velocity dispersion. Position–velocity diagrams further indicate organized rotational motions, exhibiting a compact velocity structure with a central peak and systematic gradients. Rotational temperature analysis yields = 360.6 ± 34.8 K for CH3CN, tracing the hottest and densest gas and Trot = 138 ± 45 K for CH3 13CN, consistent with cooler and more extended material. Together, these results demonstrate that G350.29+0.12 A is a rotating hot molecular core undergoing active high-mass star formation.