As a rarefied metallic element, strontium (Sr) is susceptible to significant environmental radioactive contamination risks during industrial mining and refining processes. In this study, NaA molecular sieves were prepared by alkali excitation using synthetic powders, which were homogeneously blended with the polyacrylonitrile (PAN) matrix, and nanoscale TiO2 reinforcing phases were introduced. Finally, composite separation membranes (TiO2-NaA@PANMs) with stable adsorption properties were constructed by electrostatic spinning technology. The micro-morphology and interfacial properties were characterized by SEM, XRD, and FT-IR systems. The adsorption experiments demonstrated that the equilibrium adsorption capacity of the system for Sr2+ reached 55.00 mg/g at the optimized pH = 6.0, and the theoretical saturated adsorption capacity at 298 K was 80.89 mg/g. The isothermal process conformed to the Langmuir’s model of monomolecular layer adsorption, and the kinetic behavior followed the quasi-secondary kinetic equation. Following three cycles of regeneration by elution with a 0.3 mol/L sodium citrate solution, the membrane material exhibited 81.60% Sr2+ removal efficacy. The composite membrane passages exhibited remarkable potential for utilization in engineering applications involving the treatment of complex nuclear wastewater.
Dragon fruit comprises a wide variety of species that are rich in nutritional value and have great economic potential; however, numerous studies have focused on their nutritional and commercial quality. In contrast, few studies have addressed their flavor quality, particularly with respect to the regulatory networks responsible for their flavor-related substance contents. To this end, we sequenced the transcriptomes and metabolomes of red-skin/white-fleshed and red-skin/red-fleshed dragon fruit at different timepoints during fruit development. RNA-seq and metabolome data were used to divide the seven developmental stages of the dragon fruit into four categories (young fruit, expansion, maturity, and senescence). In all, 16,827 differentially expressed genes (DEGs), including 958 transcription factors, were identified and grouped into 10 clusters, and the pathways in each cluster were annotated. Additionally, 318 differentially accumulated metabolites (DAMs) were identified, including 88 common metabolites. The main flavor-related substances and the key genes regulating them were determined via joint analysis via RNA-seq and metabolomics. Furthermore, 10 volatile active components related to green flavors and aromas were screened according to the relative odor activity value (ROAV), and 15 candidate genes related to key flavor compounds were screened via WGCNA, 3 of which encoded transcription factors. In conclusion, our results provide a theoretical basis for an in-depth understanding of the volatile flavor compounds in dragon fruit and provide new genetic resources for the subsequent study of fruit flavor compounds.
High-entropy perovskite oxides attract considerable attention due to their outstanding properties and extensive applications. In this work, the lattice distortion and the mechanical, thermal and electronic structure properties of high-entropy (Ca0.2Sr0.2Ba0.2La0.2Pb0.2)TiO3 (CSBLPT) are investigated through first-principles calculations. The results suggest that the influence of O atoms on lattice distortion is predominant, and the effect of overall A-site atoms plays a distinctly greater role than that of the B-site atoms. The mechanical results show that the high-entropy CSBLPT has a lower Young’s modulus and higher fracture toughness than ternary SrTiO3. The Debye temperature also indirectly indicates that the thermal expansion coefficient of the studied high-entropy perovskite is greater than that of SrTiO3. As for thermal conductivity, the obtained result of CSBLPT is also appreciably lower than that of SrTiO3, and the lowest thermal conductivity is along the [100] direction. The Fermi level of high-entropy CSBLPT is transferred to the conduction band, exhibiting a degenerate n-type semiconductor behavior with metallic-like characteristics, and the Bader charge values are also related to the local lattice distortion, which may cause differences in thermomechanical properties between high-entropy CSBLPT and SrTiO3. Above all, high-entropy CSBLPT is a preferable TBC material with excellent performance under working conditions compared to SrTiO3.