Liquid carbon dioxide blasting technology as a new environmentally safe rock cracking technology has been widely used in mining, enhancing the permeability of coal seam, road construction, and other fields. In this study, a liquid carbon dioxide blasting experiment was conducted on a concrete specimen of size 500mm×500mm×400 mm firstly, and the crack distribution and blast hole morphology were observed. Then, the peridynamics model of rock fracturing under liquid carbon dioxide blasting was established, and the crack propagation in liquid carbon dioxide blasting and the influence of explosion pressure and numbers and radii of releasing holes on the liquid carbon dioxide blasting effects were analyzed. The results showed that the broken concrete specimen had no obvious smash district and the direction of crack propagation was perpendicular to that of carbon dioxide release after liquid carbon dioxide blasting. The failure of the specimen was only caused by the blasting stress wave, and the quasi-static effect of high-pressure carbon dioxide did not have sufficient time to play its role. With an increase in the stress wave strength and the numbers and radii of releasing holes, the fracturing velocity of liquid carbon blasting will increase. The cracks produced by liquid carbon dioxide blasting were mainly distributed in the middle of the adjacent releasing holes. The research results had a good guiding significance for understanding the mechanism of liquid carbon dioxide rock breaking and optimizing and improving the liquid carbon dioxide fracturing device.

The strength and consistency of cemented paste backfill (CPB) are of key concerns in the stope stability and cost control for underground mines. It is common practice to use additives, such as superplasticizer, to improve the performance of CPB. This study mainly focuses on the effects of superplasticizer on the hydration, consistency, and strength of CPB. In this study, a polynaphtalene sulfonate was used as the superplasticizer. The binder is a mix of 33.3% ordinary Portland cement and 66.7% fly ash. The CPB specimens with a tailings-binder ratio of 3:1 and a solid concentration of 70% were then tested by a low field nuclear magnetic resonance system after different hydration times. Effects of polynaphtalene sulfonate on the hydration, fluidity, and strength were investigated. Results showed that the polynaphtalene sulfonate has a strong influence on short-duration hydration, which may contribute to the strength increase of CPB. It has been demonstrated that the polynaphtalene sulfonate improved the fluidity of the CPB mixture. With the increased dosage of polynaphtalene sulfonate, the slump increased. It was also found that the polynaphtalene sulfonate dosage has a negligible effect on the 1 day (d) strength while it has a strengthening effect on the 7 d, 14 d, and 28 d strength of CPB specimens.

In this study, the relationship between the pore structure and macroscopic mechanical characteristics of coarse-grained soils from mine dumps is explored under various freeze–thaw cycles. A series of experiments were conducted on the mine dump materials using a standard cube sample of 7 cm × 7 cm × 7 cm, a moisture content of 7.5%, and a density of 2.34 g/cm³. The pore structure test and uniaxial compressive strength test were carried out on the coarse-grained soil samples under different freeze–thaw cycles by using a nuclear magnetic resonance (NMR) instrument and a universal servo material testing machine. The study explores the change law of the strength and pore structure of coarse-grained soil, and establishes the correlation model between the pore structure and mechanical characteristics. The results showed that: (1) With the increase in the number of freeze–thaw cycles, the porosity of the coarse-grained soil gradually increased, and the bonding ability between the internal soil particles weakened, resulting in a decrease in strength. (2) With the increase in freeze–thaw cycles, the proportion of pore volume of the main peak and secondary peak 2 of T-2 spectrum curve increases gradually, and the internal pore structure of coarse-grained soil gradually develops towards medium and large pores. (3) There is an exponential function between the variation of pore volume proportion of each peak of coarse-grained soil and the relative strength value, and there is a good fitting coefficient between the two, indicating that the change of pore structure can well reflect the evolution law of strength.

Freeze-thaw weathering changes the pore structure, permeability, and groundwater transportation of rock material. Meanwhile, the change in rock material structure deduced by frost heaving deteriorates mechanical properties of rock material, leading to instability and insecurity of mine slopes in cold regions. In this paper, rock-like specimens containing prefabricated cracks at different angles and having undergone various freeze-thaw cycles are used as the object. Their pore structure, compressive mechanical properties, strain energies, failure characteristics, and the connection between pore structure and mechanical properties are analyzed. Results show that the porosity, spectrum area of mesopores, and spectrum area of macropores increase with the increase in freeze-thaw cycles, while crack angle shows no obvious influence on pore structure. Peak stress and elastic modulus drop with the increase in freeze-thaw cycles, while peak strain shows an increasing trend. Peak stress and elastic modulus decrease in the beginning, and then increase with the increase in crack angle, while peak strain shows a reverse trend. Elastic strain energy and pre-peak strain energy drop with the increase in freeze-thaw cycles. Elastic strain energy decreases first, and then increases with the increase in crack angle. The correlation between the spectrum area of macropores and elastic modulus is the strongest among different pores. Elastic modulus and peak stress decrease with the increase in macropore spectrum area, and peak strain increases with the increase in macropore spectrum area.

Microscopic characteristics greatly affect mechanical and physical properties as they exert vital impact on the stability and durability of materials. In this paper, widely distributed sandstone was chosen as the research object. Sandstone was treated with a coupled effect of Freeze–Thaw (F–T) weathering and acid solution, where freeze–thaw cycles were set as 0, 10, 20, 30 and 40 cycles, and the pH of the acid solution were set as 2.8, 4.2, 5.6 and 7.0, respectively. Then, nuclear magnetic resonance was applied to measure the microscopic characteristics of sandstone, then porosity, pore size distribution and permeability before the fractal dimensions were obtained and calculated. Results show that porosity increases when F–T cycles increase, and its increase grows with the pH of acid solution decrease during the first 10 F–T cycles. Macro porosity, meso porosity and micro porosity account for the largest, second largest and smallest ratio of porosity growth. Meso porosity, micro porosity and macro porosity account for the largest, second largest and smallest ratio of total porosity. Permeability increases obviously with F–T cycle increase, while acid erosion exerts little influence on permeability increment overall. Fractal dimensions of meso pores and macro pores increase with F–T cycle increase overall, and they increase with pH decrease overall. Porosity has strong exponentially correlation with permeability. Fractal dimensions of meso pores and macro pores have good linearly correlation with permeability, while correlation between porosity and fractal dimensions are not that obvious.