This communication reports on hydrogen evolution reaction (HER), studied at Ni foam and Pd-activated nickel foam materials in 0.1-M NaOH solution over the temperature range of 20–60 °C. Catalytic modification of Ni foam leads to significant facilitation of temperature-dependent HER kinetics, manifested through radically reduced values of charge-transfer resistance parameter, as well as substantially modified Tafel polarization curves. The presence of a catalytic additive (Pd) is evidenced through scanning electron microscopy (SEM) analysis.

This paper reports on the process of industrial-type wastewater purification carried-out through continuous anodic dissolution of aluminum alloy sacrificial anode for artificially aerated Cu-Al alloy galvanic (macro-corrosion) cells and synthetically prepared wastewater solutions. Electrochemical experiments were performed by means of a laboratory size electrolyzer unit, where the electrocoagulation process along with surface-induced electrooxidation phenomena were examined for wastewater containing Acid Mixture and Disperse Red 167 dyes. Final reduction of the dyes concentrations came to 32 and 99% for Acid Mixture and Disperse Red 167, correspondingly. The above was visualized through the employment of electrochemical (cyclic voltammetry and a.c. impedance spectroscopy techniques) and instrumental spectroscopy analyses.

This work is a review of scientific papers on the influence of temperature (T) on the biosorption of various dyes from aqueous solutions and wastewaters. The dyeing process of textiles is usually carried out at high temperatures, and therefore, the wastewater generated there when entering the treatment plant may still be hot. Hence, depending on the climatic conditions of a given region, the biosorption method used for their purification may occur at various temperatures. Most of the papers clearly stated the positive influence of T on biosorption, generally indicating the chemical nature of this process. At the same time, substantial number of authors confirmed the positive effect of T on the biosorption with an initial T-rise from approximately 20 °C to about 30–40 °C range; conversely, at higher temperatures, they indicated a decrease in the biosorption efficiency. Additionally, many authors clearly implied the negative impact of T on the biosorption parameters. They generally envisaged the physical nature of this process, but also indicated its limitation, as there was only a 15%–50% reduction in biosorption efficiency with an increase in T. In addition, an attempt was made to analyse the effect of temperature on the biosorption process, depending on the type of dye. It could then be cautiously suggested that a moderate increase in the T parameter favourably affected the biosorption of the red and reactive dyes.

This study investigated how anode electrode modification with iron affects the microbiome and electricity generation of microbial fuel cells (MFCs) fed with municipal wastewater. Doses of 0.0 (control), 0.05, 0.1, 0.2, and 0.4 g Fe₂O₃ per the total anode electrode area were tested. Fe₂O₃ doses from 0.05 to 0.2 g improved electricity generation; with a dose of 0.10 g Fe₂O₃, the cell power was highest (1.39 mW/m²), and the internal resistance was lowest (184.9 Ω). Although acetate was the main source of organics in the municipal wastewater, propionic and valeric acids predominated in the outflows from all MFCs. In addition, Fe-modification stimulated the growth of the extracellular polymer producers Zoogloea sp. and Acidovorax sp., which favored biofilm formation. Electrogenic Geobacter sp. had the highest percent abundance in the anode of the control MFC, which generated the least electricity. However, with 0.05 and 0.10 g Fe₂O₃ doses, Pseudomonas sp., Oscillochloris sp., and Rhizobium sp. predominated in the anode microbiomes, and with 0.2 and 0.4 g doses, the electrogens Dechloromonas sp. and Desulfobacter sp. predominated. This is the first study to holistically examine how different amounts of Fe on the anode affect electricity generation, the microbiome, and metabolic products in the outflow of MFCs fed with synthetic municipal wastewater.