Engineering is a powerful instrument for promoting the social and economic development of nations. Its enhancement is a strategic element to accelerate Brazil’s progress. This paper aims to present a new perspective on the topic of “Engineering and Development in Brazil, Challenges and Prospects” (Guimarães et al., 2007). Its goal is to discuss the need for restructuring the Brazilian system for research, development and innovation (RD&I) and the training of human resources in engineering in the country. This article is designed to discuss the relations between the performance of the industrial sector and the maturation of engineering in Brazil by looking at the national scientific production in the area in comparison to the world production and to countries (South Korea and The Netherlands). Finally, in terms of training human resources, the Brazilian study abroad program Science without Borders program is discussed in the article as an important tool for the qualification of engineering students in Brazil. A few of the main findings in this research are as follows: despite being among the top 20 countries in scientific production in Engineering, Brazil still lacks turning this scientific-technological knowledge into products and patents; Brazilian universities and research institutes must build interorganizational collaborations with the industrial sector to increase innovation in the field of engineering; The distribution of the investment in RD&I in engineering must be strategically distributed among its various fields, taking into account national strategies and the technological interrelations between them. The article concludes that engineering is a powerful instrument for promoting a country’s social development while offering indications about Brazilian strategic orientation in the development of engineering. Despite already being well known that engineering is a powerful instrument for promoting a country’s social development, this article innovates by associating academic scientific production in engineering to other variables related to economic development, such as gross domestic product, human development index, industrial and manufactured production and the filing of patents. It comes at an important moment when the Brazilian Government is discussing new strategies to increase social and economic development in the country while controlling for the investment in RD&I. Therefore, it is the right moment to discuss national policies in science, technology and innovation, especially in the area of engineering.
Polyamides (PAs) are widely used as barrier materials in offshore oil and gas (O&G) equipment due to their mechanical strength and chemical resistance. However, long-term exposure to hydrogen sulfide scavengers (H2S-SCVs) may significantly affect their physicochemical properties. Previous studies using thermal analysis and 1H time-domain NMR (1H TD-NMR) suggest that ethoxylated H2S-SCVs impose molecular constraints, increasing the glass transition temperature (Tg) and reducing chain mobility above Tg. The present study builds upon these findings using a multi-technique analytical approach, including FTIR, Raman, 1H DQ-TD-NMR, and 13C solid-state NMR (ssNMR), to provide a more comprehensive understanding of the molecular alterations in PA materials. The results clearly demonstrate that H2S-SCV exposure leads to the progressive exudation of plasticizers from the PA matrix. This plasticizer loss is a key factor contributing to the observed shift in Tg and the reduction in molecular mobility. 1H DQ-TD-NMR data confirmed an increase in the density of dynamically constrained chains over time and allowed for the characterization of heterogeneity in these constraints throughout the PA matrix. Moreover, 13C ssNMR spectra revealed the presence of immobilized H2S-SCV chemical groups within the polymer matrix, strongly supporting the early statement that the mobility constraints observed in 1H DQ-TD-NMR are associated with the formation of crosslinks induced by the H2S-SCV: H2S-SCV acts as a crosslinking agent. Taken together, our findings indicate that both plasticizer loss and H2S-SCV-induced crosslinking contribute significantly to the microstructural evolution of PAs when exposed to ethoxylated H2S-SCVs, offering important insights into their degradation mechanisms and long-term behavior in aggressive operational environments.