We report the procedure for hydrothermal synthesis of ultrasmall Yb³⁺/Tm³⁺ co-doped Sr₂LaF₇ (SLF) upconversion phosphors. These phosphors were synthesized by varying the concentrations of Yb³⁺ (x = 10, 15, 20, and 25 mol%) and Tm³⁺ (y = 0.75, 1, 2, and 3 mol%) with the aim to analyze their emissions in the near IR spectral range. According to the detailed structural analysis, Yb³⁺ and Tm³⁺ occupy the La³⁺ sites in the SLF host. The addition of Yb³⁺/Tm³⁺ ions has a huge impact on the lattice constant, particle size, and PL emission properties of the synthesized SLF nanophosphor. The results show that the optimal dopant concentrations for upconversion luminescence of Yb³⁺/Tm³⁺ co-doped SLF are 20 mol% Yb³⁺ and 1 mol% Tm³⁺ with EDTA as the chelating agent. Under 980 nm light excitation, a strong upconversion emission of Tm³⁺ ions around 800 nm was achieved. In addition, the experimental photoluminescence lifetime of Tm³⁺ emission in the SLF host is reported. This study discovered that efficient near IR emission from ultrasmall Yb³⁺/Tm³⁺ co-doped SLF phosphors may have potential applications in the fields of fluorescent labels in bioimaging and security applications.

Sr₂LaF₇:xPr³⁺ (x = 0.2, 1, 2, 3, 5, 10, and 25 mol%) nanophosphors with a cubic Fm3m structure were hydrothermally synthesized, forming nearly spherical nanoparticles with an average diameter of approximately 32 nm. Diffuse reflectance measurement and excitation spectra showed a primary excitation peak of Pr³⁺ at 443 nm, corresponding to the ground state to the ³P₂ level transition. Upon blue light excitation, Pr³⁺-activated Sr₂LaF₇ nanophosphors showed rich emission structure across the visible region of the spectrum, with blue (~483 nm), green (~525 nm), orange (~600 nm), and red (~640 nm) emissions, blue and orange being the most prominent ones. The relative intensities of these emissions varied with Pr³⁺ concentration, leading to tunable emission colors. The chromaticity showed slight variation with the Pr³⁺ content (0.350 < x < 0.417, 0.374 < y < 0.380), while the CCT value increased from 3118 K to 4901 K as the doping concentration increased. The optimized Sr₂LaF₇ with 2 mol% Pr³⁺ had the most intense emission with correlated color temperature (CCT) of 3628 K, corresponding to the warm white color. The proposed Pr³⁺-doping strategy offers valuable insights into discovering or optimizing single-phase phosphors for white-light-emitting applications.