The extremely high levels of water pollution caused by various industrial activities represent one of the most important environmental problems. Efficient techniques and advanced materials have been extensively developed for the removal of highly toxic organic pollutants, including pesticides. This study investigated the photocatalytic degradation of the fungicide carbendazim (Czm) using composite track-etched membranes (TeMs) in an aqueous solution. Copper(I) oxide (Cu₂O) and zinc oxide (ZnO) microtubes (MTs) were prepared using an electroless template deposition technique in porous poly(ethylene terephthalate) (PET) TeMs with nanochannels with a density of 4 × 10⁷ pores/cm⁻² and diameter of 385 ± 9 nm to yield Cu₂O@PET and ZnO@PET composite membranes, respectively. A mixed Cu₂O/ZnO@PET composite was prepared via a two-step deposition process, containing ZnO (87%) and CuZ (13%) as crystalline phases. The structure and composition of all composite membranes were elucidated using scanning electron microscopy (SEM), atomic force microscopy (AFM), energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) techniques. Under UV–visible light irradiation, the Cu₂O/ZnO@PET composite displayed enhanced photocatalytic activity, reaching 98% Czm degradation, higher than Cu₂O@PET and ZnO@PET composites. The maximum Czm degradation efficiency from aqueous solution was obtained at an optimal pH of 6 and contact time of 140 min. The effects of various parameters such as temperature, catalyst dosage and sample exposure time on the photocatalytic degradation process were studied. The degradation reaction of Czm was found to follow the Langmuir–Hinshelwood mechanism and a pseudo-first order kinetic model. The degradation kinetics of Czm accelerated with increasing temperature, and the activation energy (E_a) levels were calculated as 11.9 kJ/mol, 14.22 kJ/mol and 15.82 kJ/mol for Cu₂O/ZnO@PET, ZnO@PET and Cu₂O@PET composite membranes, respectively. The reusability of the Cu₂O/ZnO@PET catalyst was also investigated at different temperatures for 10 consecutive runs, without any activation or regeneration processes. The Cu₂O/ZnO@PET composite exhibited degradation efficiency levels of over 50% at 14 °C and over 30% at 52 °C after 5 consecutive uses.

This paper reports the synthesis of composite track-etched membranes (TeMs) modified with electrolessly deposited copper microtubules using copper deposition baths based on environmentally friendly and non-toxic reducing agents (ascorbic acid (Asc), glyoxylic acid (Gly), and dimethylamine borane (DMAB)), and comparative testing of their lead(II) ion removal capacity via batch adsorption experiments. The structure and composition of the composites were investigated by X-ray diffraction technique and scanning electron and atomic force microscopies. The optimal conditions for copper electroless plating were determined. The adsorption kinetics followed a pseudo-second-order kinetic model, which indicates that adsorption is controlled by the chemisorption process. A comparative study was conducted on the applicability of the Langmuir, Freundlich, and Dubinin–Radushkevich adsorption models to define the equilibrium isotherms and the isotherm constants for the prepared composite TeMs. Based on the regression coefficients R², it has been shown that the Freundlich model better describes the experimental data of the composite TeMs on the adsorption of lead(II) ions.

Cu@PC, Ni ₂ O ₃ @PC as well as Cu/Ni ₂ O ₃ @PC mixed composite track-etched membranes were synthesized using an electroless deposition technique and demonstrated enhanced photocatalytic degradation capacity for norfloxacin.

Effective removal of toxic inorganic and organic pollutants is one of the current leading challenges of wastewater treatment. In this study, the decomposition of methylene blue (MB) under UV light irradiation was investigated in the presence of copper nanoclusters (NCs)-deposited polyethylene terephthalate (PET) track-etched hybrid membranes. PET track-etched membranes (TeMs) with an average pore size of ~400 nm were grafted by functional acrylic acid (AA) monomer under electron beam irradiation after oxidation with H₂O₂/UV system. The radiation dose varied between 46 and 200 kGy. For the deposition of copper NCs, poly(acrylic acid) (PAA)-grafted membranes saturated with Cu(II) ions were irradiated either by electron beam or γ-rays to obtain copper-based NCs for the catalytic degradation of MB. Irradiation to 100 kGy with accelerated electrons resulted in the formation of small and uniform copper hydroxide (Cu(OH)₂) nanoparticles homogeneously distributed over the entire volume of the template. On the other hand, irradiation under γ-rays yielded composites with copper NCs with a high degree of crystallinity. However, the size of the deposited NCs obtained by γ-irradiation was not uniform. Nanoparticles with the highest uniformity were obtained at 150 kGy dose. Detailed analysis by X-ray diffraction (XRD) and scanning electron microscopy (SEM) confirmed the loading of copper nanoparticles with an average size of 100 nm on the inner walls of nanochannels and on the surface of PET TeMs. Under UV light irradiation, composite membranes loaded with NCs exhibited high photocatalytic activity. It was determined that the highest catalytic activity was observed in the presence of Cu(OH)₂@PET-g-PAA membrane obtained at 250 kGy. More than 91.9% of the initial dye was degraded when this hybrid membrane was employed for 180 min, while only 83.9% of MB was degraded under UV light using Cu@PET-g-PAA membrane. Cu(OH)₂@PET-g-PAA membranes obtained under electron beam irradiation demonstrated a higher photocatalytic activity compared to Cu@PET-g-PAA membranes attained by γ-rays.

Developing novel membranes marks a significant advancement in flexible energy storage systems. In this work, a hybrid track-etched membrane (TeM) was synthesized through RAFT-mediated polymerization, where poly(acrylic acid) (PAA) was grafted onto both the nanopore walls and surface of PET-based TeMs (PET-g-PAA), creating a stable and functionalized matrix for further enhancements. The membrane was then modified by incorporating electrospun composite nanofibers made from poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) as the polymer matrix, ionic liquid (1-ethyl-3-methylimidazolium tetrafluoroborate, EM-IMBF4) as the supporting electrolyte, and graphene oxide (GO) as the ionic conductivity enhancer. The nanofibers (PVDF-HFP_GO) were deposited on either one or both surfaces of the grafted membrane. These modifications substantially improved the membrane's active surface area, porosity, and electrochemical performance, positioning it as a strong candidate for flexible energy storage applications. Comprehensive characterizations verified the successful modification and enhanced properties, including FTIR, SEM-EDX, XPS, TGA, porosity analysis, and contact angle measurements. Electrochemical performance was evaluated through cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS). Among the tested membranes, the one modified with 0.5% GO-containing nanofibers demonstrated the highest capacitance and coulombic efficiency. Although the membrane showed strong charge/discharge efficiency and high initial performance, performance degradation was observed after extended cycling, particularly at higher current densities. The ionic conductivity of the hybrid membranes (with a GO concentration of 0.5%) reaches 14.83 × 10⁻³ mS cm⁻¹ for single-sided nanofiber-covered membranes and 39.08 × 10⁻³ mS cm⁻¹ for double-sided nanofiber-covered membranes, while for similar samples without addition of GO this values were found to be of 1.42 × 10⁻³ mS cm⁻¹, which is significantly higher than conventional polymer-based electrolyte membranes (∼10⁻⁴ to 10⁻² mS cm⁻¹), and comparable to advanced ionic gel-based systems (∼10⁻² to 10⁻¹ mS cm⁻¹). The synergistic effects of PAA grafting and PVDF-HFP_GO fibers delivered competitive charge/discharge efficiency when compared to similar systems, though further optimization of current density and cycling stability is required. This study highlights the potential of combining the RAFT-mediated grafting technique with electrospun composite nanofibers in modifying TeMs to develop durable and flexible supercapacitor membranes with promising electrochemical performance.