In the present context of mitigating greenhouse gas emissions, interground portland-limestone cement (PLC) with elevated limestone filler (LF) replacement ratios (exceeding 15%) presents a feasible sustainable alternative, capable of diminishing clinker content. While LFs are known to modify the microstructure of concrete, the influence on ASR development has yet to be fully understood and requires further investigation. In this context, this work evaluates the effect of LFs replacement ratios between 15% and 25% on ASR development in concrete mixtures incorporating PLC. Analysis of expansion from accelerated mortar bar tests (AMBT) and concrete prism tests (CPT) indicate that increasing LF content from 15% to 25% does not substantially affect ASR-induced expansion. These findings underscore the viability of PLC as a sustainable construction material that does not compromise durability concerning ASR.

The critical climate change has raised concern about the decarbonization of the cement and concrete industry, which is responsible for 8% of global CO2 emissions. Portland limestone cement (PLC), which is made by partially replacing the clinker with up to 15% interground limestone fines (LFs), has been recognized as a viable solution for its feasibility to match the engineering properties of ordinary portland cement (OPC). However, with the necessity of further increasing the LFs contents to meet the desired eco-efficiency, the dilution effect brought by less ultimate hydration products may be detrimental to the long-term performance of reinforced concrete structures, such as chloride-induced corrosion. Thus, this research explores the potential of combining PLC and alumina-rich supplementary cementitious materials (SCMs) to improve the resistivity of the concrete. Concrete specimens were fabricated with PLCs from two sources of three LFs replacement ratios (15, 20, and 25%). MK (8%) is used as the source of alumina. The bulk and surface resistivity results showed that combining PLC with MK can notably improve concrete resistivity even in mixtures with lower amounts of cement. Additionally, compressive strength demonstrated poor correlation with electrical resistivity, which highlights the significance of performance-based design.