The martensitic transformation mechanism in the heat-affected zone of DP1180 steel plays a decisive role in the strength of welded joints. In this work, the nucleation and growth kinetics of martensite laths in the coarse grain heat-affected zone (CGHAZ) are analyzed by a high-temperature laser scanning confocal microscope (LSCM). The grain distribution and stress distribution of the samples after in situ observation are analyzed by electron backscatter diffraction (EBSD). The results reveal that austenite grain growth is realized by continuous grain boundary annexation and grain boundary migration of small grains by large grains during the heating process. Seven growth modes of CGHAZ martensitic laths under laser welding conditions are proposed. Additionally, the end growth of martensitic laths is mostly attributed to the collision with grain boundaries or other laths to form a complex interlocking structure. The results of this study could provide important data support for the development of dual-phase steel materials and improvement of welding quality.
Residual particles embedded at the bond coat/substrate (BC/SUB) interface after grit blasting can affect the failure behavior of thermal barrier coatings (TBCs) under thermal cycling. This study employed a 2D finite element model combining the cohesive zone method (CZM) and extended finite element method (XFEM) to analyze the effect of interfacial grit particles. Specifically, the CZM was used to simulate crack propagation at the BC/thermally grown oxide (TGO) interface, while XFEM was applied to model the arbitrary crack propagation within the BC layer. Three models were analyzed: no grit inclusion, 20 μm grit particles, and 50 μm grit particles at the BC/SUB interface. This systematic variation allowed isolating the influence of particle size on the location of crack propagation onset, stress distribution, and crack growth behavior. The results showed that grit particles at the SUB/BC interface had negligible influence on the crack propagation location and rate at the BC/TGO interface, due to their spatial separation. However, their presence significantly altered the radial tensile stress distribution within the BC layer. Larger grit particles induced more intense stress concentrations and promoted earlier and more extensive vertical crack propagation within the BC. However, due to plastic deformation and stress redistribution in the BC, the crack propagation was progressively suppressed in the later stages of thermal cycling. Overall, grit particles primarily promoted vertical crack propagation within the BC layer. Optimizing grit blasting to control grit particle size is crucial for improving the durability of TBCs.
Growth kinetics and the irreversible deformation of thermally growth oxide (TGO) critically affect the delamination and cracking at the interface of thermal barrier coatings (TBCs). In this study, TGO dynamic growth during furnace cycles is simulated using three different approaches. The stress evolution and damage characteristics near the interface are compared in various TGO growth modes. Furthermore, the influences of TGO creep at high temperatures on the interface delamination and coating failure are also investigated. The results reveal that TGO growth achieved through material transformation (growth mode III) leads to earlier interface delamination compared to element swelling methods (growth mode I and II). Although the stress value in growth mode II is higher than that in growth mode I after all cycles, earlier delamination and spallation occur in mode I due to faster stress accumulation in the initial stage of thermal cycle. Moreover, rapid TGO creep is found to reduce the accumulated stress within the ceramic layer and delay the onset of interface delamination. These findings provide important theoretical insights for the development and life assessment of advanced TBCs.
Thermal shock resistance is a critical parameter for evaluating the long-term service reliability of protective coatings in high-temperature molten-salt environments. In this study, Al2O3–Y2O3 composite coatings containing 0, 2, 5, and 8 wt.% Y2O3 were fabricated on 316L stainless-steel substrates by atmospheric plasma spraying (APS). Their phase constitution, microstructure, mechanical properties, and thermal shock resistance were systematically investigated. The results showed that, with increasing Y2O3 content, the relative content of α-Al2O3 gradually increased, whereas the coating densification, microhardness, and fracture toughness first increased and then decreased. After 200 thermal shock cycles, the thermal shock resistance of the Al2O3–Y2O3 composite coatings followed the order of 5 wt.% Y2O3 > 2 wt.% Y2O3 > 8 wt.% Y2O3 > 0 wt.% Y2O3, indicating that the addition of an appropriate amount of Y2O3 significantly improves the thermal shock resistance of the coatings. Analysis of the failure mechanism further revealed that the addition of an appropriate amount of Y2O3 enhanced phase stability and optimized the coating microstructure, thereby improving the crack-propagation resistance and ultimately enhancing the thermal shock resistance. In contrast, excessive Y2O3 weakens this beneficial effect because of increased microstructural heterogeneity and a higher defect density.
Residual grit particles introduced during grit blasting are important process-induced defects that can significantly affect the interfacial damage evolution of thermal barrier coatings (TBCs) under thermal cycling; however, the coupled effects of thermally grown oxide (TGO) amplitude, grit size, and grit position on crack propagation in the bond coat (BC) remain insufficiently understood. In this work, a two-dimensional finite element model containing residual alumina grit particles was established to investigate the influence of these three factors on the radial stress distribution and crack growth behavior in the BC, and their individual contributions and interaction effects were further quantified using response surface methodology. The results showed that TGO morphology and interfacial grit defects jointly controlled the stress concentration and crack propagation behavior in the BC. Increasing the TGO amplitude intensified the radial tensile stress concentration in the BC and gradually shifted the critical stress region during thermal cycling. Larger grit particles further aggravated the local stress concentration near the grit tips, while the movement of grit particles toward the TGO peak led to a more pronounced increase in stress concentration and crack propagation tendency. The crack growth behavior was found to be consistent with the corresponding stress evolution characteristics. Response surface analysis further revealed that grit size and grit position had much stronger effects on crack propagation than TGO amplitude, and their interaction was the most significant among all factor combinations. The minimum crack length in the BC layer was obtained at a TGO amplitude of 0.01 mm, a grit size of 20 μm, and a position parameter of 0.752, and the predicted value agreed well with the finite element result. This study provides a comparative basis for interfacial damage assessment and grit-blasting parameter optimization in TBCs containing residual grit defects.
The intrinsic defects in thermal barrier coating (TBC) seriously affect its thermal insulation performance and service life. In this work, four typical TBC models are developed based on the same image to quantitatively compare the effects of defects on insulation and interface damage. The coupling behavior of thermally grown oxide (TGO) and gradient thermal cycling is considered. The propagation and evolution of intrinsic, pore edge, and interface cracks in the multi-defect model are explored. Results indicate that intrinsic cracks cause a temperature difference of up to 15 °C on the flat coating surfaces. Intrinsic defects have no effect on interface temperature. Compared to the defect-free model, intrinsic cracks result in a maximum increase of 70% in normal stress near the interface and a 48% increase in shear stress. The fully damaged area in the POR-CR model is 40% higher than that in the HOM model. Based on the POR-CR model, which is closer to the real microstructure, the merging methods of internal and interface cracks are summarized into six types. The relevant results can provide important data support for a comprehensive understanding of the failure mechanism of in-service coatings and accurate prediction of service life.