Geopolymers have the advantages of low carbon, being environmentally friendly and low price, which matches the development direction of building materials. Common geopolymer materials are also known as two-part geopolymers (TPGs). TPGs are usually prepared from two main substances, which are formed by polymerization of a silicoaluminate precursor and an alkaline activator solution. The TPG has many limitations in engineering application because of its preparation on the construction site, and the use of solid alkaline activator in one-part geopolymers (OPGs) overcomes this shortcoming. However, the brittleness of OPGs such as ceramics also hinders its popularization and application. The properties of the new OPG can be improved effectively by toughening and strengthening it with fibers. This review discusses the current studies of fiber-reinforced one-part geopolymers (FOPGs) in terms of raw precursors, activators, fibers, physical properties and curing mechanisms. In this paper, the effects of the commonly used reinforcement fibers, including polyvinyl alcohol (PVA) fiber, polypropylene (PP) fiber, polyethylene (PE) fiber, basalt fiber and other composite fibers, on the fresh-mixing properties and mechanical properties of the OPGs are summarized. The performance and toughening mechanism of FOPGs are summarized, and the workability, macroscopic mechanical properties and durability of FOPGs are investigated. Finally, the development and engineering application prospect of FOPGs are prospected.
Geopolymer (GP) is environmentally friendly, has good mechanical properties and long-term workability, and has broad application prospects. However, due to the poor tensile strength and toughness of GPs, they are sensitive to microcracks, which limits their application in engineering. Fiber can be added to GPs to limit the growth of cracks and enhance the toughness of the GP. Plant fiber (PF) is cheap, easy to obtain, and abundant in source, which can be added to GP to improve the properties of composites. This paper reviews recent studies on the early properties of plant fiber-reinforced geopolymers (PFRGs). In this manuscript, the properties of PFs commonly used for GP reinforcements are summarized. The early properties of PFRGs were reviewed, including the rheological properties of fresh GPs, the early strength of PFRGs, and the early shrinkage and deformation properties of PFRGs. At the same time, the action mechanism and influencing factors of PFRGs are also introduced. Based on the comprehensive analysis of the early properties of PFRGs, the adverse effects of PFs on the early properties of GPs and the solutions were summarized.
This research focuses on improving the characteristics of recycled concrete and utilizing solid waste resources through the combination of industrial waste pre-impregnation and the carbonation process. A novel pre-impregnation–carbonation aggregate method is proposed to increase the content of carbonatable components in the surface-bonded mortar of recycled coarse aggregate by pre-impregnating it with carbide slag slurry (CSS). This approach enhances the subsequent carbonation effect and thus the properties of recycled aggregates. The experimental results showed that the method significantly improved the water absorption, crushing value, and apparent density of the recycled aggregate. Additionally, it enhanced the compressive strength, split tensile strength, and flexural strength of the recycled concrete produced using the aggregate improved by this method. Microanalysis revealed that CO2 reacts with calcium hydroxide and hydrated calcium silicate (C-S-H) to produce calcite-type calcium carbonate and amorphous silica gel. These reaction products fill microcracks and pores on the aggregate and densify the aggregate–paste interfacial transition zone (ITZ), thereby improving the properties of recycled concrete. This study presents a practical approach for the high-value utilization of construction waste and the production of low-carbon building materials by enhancing the quality of recycled concrete. Additionally, carbon sequestration demonstrates broad promise for engineering applications.