The road construction sector urgently requires environmentally friendly, low-carbon, and high-performance base materials. Traditional materials exhibit issues of high energy consumption and carbon emissions, making it difficult for them to align with sustainable development requirements. While slag- and fly ash-based geopolymers demonstrate promising application potential in civil engineering, research on their application in road-stabilized soils remains insufficient. To address the high energy consumption and carbon emissions associated with conventional road base materials and to fill this research gap, this study investigated the utilization of industrial solid wastes through slag-based geopolymer and fly ash as stabilizers, systematically evaluating the pavement performance of two distinct soil types. Unconfined compressive strength tests and freeze–thaw cycling tests were conducted to elucidate the effects of stabilizer dosage, fly ash co-stabilization, and compaction degree on mechanical properties. The results demonstrated that the compressive strength of both stabilized soils increased significantly with higher slag-based geopolymer content, achieving peak values of 5.2 MPa (soil sample 1) and 4.5 MPa (soil sample 2), representing a 30% improvement over cement-stabilized soils with identical mix proportions. Fly ash co-stabilization exhibited more pronounced reinforcement effects on soil sample 2. At a 98% compaction degree, soil sample 1 maintained a stable 50% strength enhancement, whereas soil sample 2 displayed a dose-dependent exponential strength increase. Freeze–thaw resistance tests revealed the superior performance of soil sample 1, showing a loss of compressive strength (BDR) of 78% with 8% geopolymer stabilization alone, which improved to 90% after fly ash co-stabilization. For soil sample 2, the BDR increased from 64% to 80% through composite stabilization. This study confirms that slag/fly ash-based geopolymer-stabilized soils not only meet the strength requirements for heavy-traffic subbases and light-traffic base courses, but also demonstrates its great potential as a low-carbon and environmentally friendly material to replace traditional road base materials.

This study used silicate cement as the base material and nano-silica, fly ash, and bentonite as the composite modification components. Through laboratory tests, the engineering characteristics and impermeability and drying shrinkage properties of the modified slurry were systematically investigated. The results showed that the verification test mix proportion of the slurry was a water–binder ratio of 0.7, a nano-silica content of 2%, a fly ash content of 40%, and a bentonite content of 6%. This ratio of the slurry had the best comprehensive performance. Compared with pure cement slurry, the water loss rate decreased by 61.90%; the 3d, 7d, and 28d compressive strengths increased by 30.60%, 36.08%, and 20.08% respectively; the fluidity decreased by 6.38%; and the initial setting time decreased by 9.77%. The anti-seepage pressure of the verification test mix proportion slurry group reached 1.05 MPa, which was 43.84% higher than the pure cement reference group and was superior to each single addition group. Combined incorporation of nano-silica, fly ash, and bentonite remarkably improved the impermeability. The 56d drying shrinkage rate was 1257 × 10⁻⁶, which was 19.16% lower than that of the reference group. Based on X-ray diffraction (XRD) and scanning electron microscopy (SEM) tests, the microstructure was analyzed, and the hydration mechanism was discussed. The composite modification did not change the type of hydration products but significantly improved the microstructure. Nano-silica reacted with the hydration product Ca(OH)₂ in the early stage of hydration, accelerating the hydration process and promoting the interwoven coating of the hydration product on the calcium aluminosilicate crystals, thereby improving the compactness of the matrix. Fly ash participated in the pozzolanic reaction in the later stage of hydration, adhering to the secondary hydration products on the surface and gradually consuming them, further filling the pores and optimizing the interface structure. Combined with bentonite, nano-silica and fly ash jointly densified the matrix, refining the microstructure of modified samples and forming a continuous integrated hydration product network inside the grout.