Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U–Pb geochronology of carbonate minerals, calcite in particular, is rapidly gaining popularity as an absolute dating method. The high spatial resolution of LA-ICP-MS U–Pb carbonate geochronology has benefits over traditional isotope dilution methods, particularly for diagenetic and hydrothermal calcite, because uranium and lead are heterogeneously distributed on the sub-millimetre scale. At the same time, this can provide limitations to the method, as locating zones of radiogenic lead can be time-consuming and “hit or miss”. Here, we present strategies for dating carbonates with in situ techniques, through imaging and petrographic techniques to data interpretation; our examples are drawn from the dating of fracture-filling calcite, but our discussion is relevant to all carbonate applications. We review several limitations to the method, including open-system behaviour, variable initial-lead compositions, and U–daughter disequilibrium. We also discuss two approaches to data collection: traditional spot analyses guided by petrographic and elemental imaging and image-based dating that utilises LA-ICP-MS elemental and isotopic map data.

Constraining the timing of brittle faulting is critical in understanding crustal deformation and fluid flow, but many regional-scale fault systems lack readily available techniques to provide absolute chronological information. Calcite mineralization occurs in crustal faults in many geological settings and can be suitable for U-Pb geochronology. This application has remained underutilized because traditional bulk dissolution techniques require uncommonly high U concentration. Because U and Pb are distributed heterogeneously throughout calcite crystals, high-spatial-resolution sampling techniques can target domains with high U and variable U/Pb ratios. Here we present a novel application of in-situ laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) to basaltic fault rock geochronology in the Faroe Islands, northeast Atlantic margin. Faults that are kinematically linked to deformation associated with continental break-up were targeted. Acquired ages for fault events range from mid-Eocene to mid-Miocene and are therefore consistently younger than the regional early Eocene onset of ocean spreading, highlighting protracted brittle deformation within the newly developed continental margin. Calcite geochronology from LA-ICP-MS U-Pb analysis represents an important and novel method to constrain the absolute timing of fault and fluid-flow events.

The characterization of the geochemical reservoirs of the Earth's continental crust, including the determination of representative upper and lower crustal compositions, underpins our understanding of crustal evolution. The classic I- and S-type granite classification has often been invoked to distinguish between melts derived from igneous protoliths and those derived from the melting of a sedimentary source. Recent geochemical studies suggest that most granites, even those cited as typical examples of ‘S-type’, show evidence for a mixture of mantle and upper crustal sources, thereby implying that granite formation is evidence for overall crustal growth. We have examined the source of leucogranite bodies in one of the world's youngest collisional orogens using novel zircon techniques that can resolve the presence of even minor mantle contributions. 232 zircons from 12 granites from the Bhutan Himalaya were analysed by in-situ techniques for O, Hf and U–Pb isotopic signatures. In combination with data from the granite host rocks, our data show that the Himalayan leucogranites were derived solely from metamorphosed crustal sediments, and do not record any mantle contribution. This finding is consistent with the time-lag between crustal thickening and widespread crustal melting, and the heat-producing capacities of the pelitic source rocks. We conclude that Himalayan leucogranites provide a more suitable type locality for ‘S-type’ granites than the Lachlan area in South-East Australia where the term was first defined. The Himalayan leucogranites therefore provide evidence that syn-orogenic melting during collisional events does not necessarily result in crustal growth. Importantly, crustal growth models should not always assume that crustal growth is achieved during collisional orogenesis

The evolution of Earth's biosphere, atmosphere and hydrosphere is tied to the formation of continental crust and its subsequent movements on tectonic plates. The supercontinent cycle posits that the continental crust is periodically amalgamated into a single landmass, subsequently breaking up and dispersing into various continental fragments. Columbia is possibly the first true supercontinent, it amalgamated during the 2.0–1.7 Ga period, and collisional orogenesis resulting from its formation peaked at 1.95–1.85 Ga. Geological and palaeomagnetic evidence indicate that Columbia remained as a quasi-integral continental lid until at least 1.3 Ga. Numerous break-up attempts are evidenced by dyke swarms with a large temporal and spatial range; however, palaeomagnetic and geologic evidence suggest these attempts remained unsuccessful. Rather than dispersing into continental fragments, the Columbia supercontinent underwent only minor modifications to form the next supercontinent (Rodinia) at 1.1–0.9 Ga; these included the transformation of external accretionary belts into the internal Grenville and equivalent collisional belts. Although Columbia provides evidence for a form of ‘lid tectonics’, modern style plate tectonics occurred on its periphery in the form of accretionary orogens. The detrital zircon and preserved geological record are compatible with an increase in the volume of continental crust during Columbia's lifespan; this is a consequence of the continuous accretionary processes along its margins. The quiescence in plate tectonic movements during Columbia's lifespan is correlative with a long period of stability in Earth's atmospheric and oceanic chemistry. Increased variability starting at 1.3 Ga in the environmental record coincides with the transformation of Columbia to Rodinia; thus, the link between plate tectonics and environmental change is strengthened with this interpretation of supercontinent history

The strong resilience of the mineral zircon and its ability to host a wealth of isotopic information make it the best deep-time archive of Earth's continental crust. Zircon is found in most felsic igneous rocks, can be precisely dated and can fingerprint magmatic sources; thus, it has been widely used to document the formation and evolution of continental crust, from pluton- to global-scale. Here, we present a review of major contributions that zircon studies have made in terms of understanding key questions involving the formation of the continents. These include the conditions of continent formation on early Earth, the onset of plate tectonics and subduction, the rate of crustal growth through time and the governing balance of continental addition v. continental loss, and the role of preservation bias in the zircon record. Supplementary material: A compilation used in this study of previously published detrital zircon U-Pb-Hf isotope data are available at http://www.geolsoc.org.uk/SUP18791