Direct measurements of the magnetocaloric effect in samples of rapidly quenched ribbons of and Heusler alloys with potential applications in magnetic refrigeration technology are carried out. The measurements were made by a precise method based on the measurement of the oscillation amplitude of the temperature in the sample while is subjected to a modulated magnetic field. In the studied compositions both direct and inverse magnetocaloric effects associated with magnetic (paramagnet-ferromagnet-antiferromagnet) and structural (austenite-martensite) phase transitions are found. Additional inverse magnetocaloric effects of small value are observed around the ferromagnetic transitions.
Highly hexagonally ordered hard anodic aluminum oxide membranes, which have been modified by a thin cover layer of SiO2 deposited by atomic layer deposition method, were used as templates for the synthesis of electrodeposited magnetic Co-Ni nanowire arrays having diameters of around 180 to 200 nm and made of tens of segments with alternating compositions of Co54Ni46 and Co85Ni15. Each Co-Ni single segment has a mean length of around 290 nm for the Co54Ni46 alloy, whereas the length of the Co85Ni15 segments was around 430 nm. The composition and crystalline structure of each Co-Ni nanowire segment were determined by transmission electron microscopy and selected area electron diffraction techniques. The employed single-bath electrochemical nanowire growth method allows for tuning both the composition and crystalline structure of each individual Co-Ni segment. The room temperature magnetic behavior of the multisegmented Co-Ni nanowire arrays is also studied and correlated with their structural and morphological properties.
Arrays of hexagonally ordered Fe28Co67Cu5 nanowires with tailored diameter from 18 to 27 nm were prepared by electroplating into anodic alumina templates and annealed in the temperature range of 300–600 °C, preserving but refining their bcc crystal structure. Despite the partial reduction of saturation magnetization and corresponding shape anisotropy after annealing at 500 °C, larger coercivity, 0.36 T, and squareness ratio, Mr/Ms = 0.98, were obtained. This unexpected behavior is interpreted through micromagnetic simulations where the magnetic hardening is associated with the transition from vortex to transverse domain-wall reversal modes connected with the reduction of saturation magnetization. Simulations also predict a significant coercivity increase with decreasing nanowires diameter which agrees with experimental data in the overlapping diameter range.