The aim of the study was to assess the content, distribution, soil binding capacity, and ecological risk of cadmium and lead in the soils of Malopolska (South Poland). The investigation of 320 soil samples from differently used land (grassland, arable land, forest, wasteland) revealed a very high variation in the metal content in the soils. The pollution of soils with cadmium and lead is moderate. Generally, a point source of lead and cadmium pollution was noted in the study area. The highest content of cadmium and lead was found in the northwestern part of the area—the industrial zones (mining and metallurgical activity). These findings are confirmed by the arrangement of semivariogram surfaces and bivariate Moran’s correlation coefficients. Among the different types of land use, forest soils had by far the highest mean content of bioavailable forms of both metals. The results showed a higher soil binding capacity for lead than for cadmium. However, for both metals, extremely high (class 5) accumulation capacities were dominant. Based on the results, the investigated soils had a low (Pb) and moderate (Cd) ecological risk on living components. Soil properties, such as organic C, pH, sand, silt, and clay content, correlated with the content of total and bioavailable forms of metals in the soils. The correlations, despite being statistically significant, were characterized by very low values of correlation coefficient (r = 0.12–0.20, at p ≤ 0.05). Therefore, the obtained data do not allow to define any conclusions as to the relationships between these soil properties. However, it must be highlighted that there was a very strong positive correlation between the total content of cadmium and lead and their bioavailable forms in the soils.

The aims of this study were to investigate zinc content in the studied soils; evaluate the efficiency of geostatistics in presenting spatial variability of zinc in the soils; assess bioavailable forms of zinc in the soils and to assess soil–zinc binding ability; and to estimate the potential ecological risk of zinc in soils. The study was conducted in southern Poland, in the Malopolska Province. This area is characterized by a great diversity of geological structures and types of land use and intensity of industrial development. The zinc content was affected by soil factors, and the type of land use (arable lands, grasslands, forests, wastelands). A total of 320 soil samples were characterized in terms of physicochemical properties (texture, pH, organic C content, total and available Zn content). Based on the obtained data, assessment of the ecological risk of zinc was conducted using two methods: potential ecological risk index and hazard quotient. Total Zn content in the soils ranged from 8.27 to 7221 mg kg⁻¹ d.m. Based on the surface semivariograms, the highest variability of zinc in the soils was observed from northwest to southeast. The point sources of Zn contamination were located in the northwestern part of the area, near the mining–metallurgical activity involving processing of zinc and lead ores. These findings were confirmed by the arrangement of semivariogram surfaces and bivariate Moran’s correlation coefficients. The content of bioavailable forms of zinc was between 0.05 and 46.19 mg kg⁻¹ d.m. (0.01 mol dm⁻³ CaCl₂), and between 0.03 and 71.54 mg kg⁻¹ d.m. (1 mol dm⁻³ NH₄NO₃). Forest soils had the highest zinc solubility, followed by arable land, grassland and wasteland. PCA showed that organic C was the key factor to control bioavailability of zinc in the soils. The extreme, very high and medium zinc accumulation was found in 69% of studied soils. There is no ecological risk of zinc to living organisms in the study area, and in 90% of the soils there were no potentially negative effects of zinc to ecological receptors.

The aims of the study were to investigate the concentration, sources and ecological risk of PAHs (polycyclic aromatic hydrocarbons) in bottom sediments collected from nine reservoirs located in south-eastern Poland. The concentration of ∑PAHs in sediments ranged from 150 to 33,900 μg kg⁻¹. The total PAH concentration in the bottom sediments was arranged in the following order: Rybnik > Rzeszów > Brzóza Królewska > Brzóza Stadnicka > Besko > Chechło > Ożanna > Głuchów > Narożniki. BAP was the major compound in sediments from the Besko, Brzóza Stadnicka and Rzeszów reservoirs; FLT in the sediments from the Rybnik, Narożniki, Ożanna and Brzóza Królewska reservoirs; and FLN from the Głuchów and Chechło reservoirs. The major inputs of PAHs were of pyrolytic origin. However, petrogenic sources of PAHs occurred especially in the Chechło and Głuchów reservoirs. The ecological risk assessment indicated that non-adverse effects on the benthic fauna may occur for sediments from the Głuchów, Narozniki and Ożanna reservoirs, while slightly adverse effects were found for sediments from the Brzóza Królewska, Besko, Brzóza Stadnicka and Chechło reservoirs. The other sediments showed moderate (Rzeszów reservoirs) and strong effect (Rybnik reservoir) on biological communities. Individual PAHs such as NAP, PHE, FLT, PYR, BAA, CHR and BAP in sediments from the Rybnik reservoir and BAP in sediments from the Rzeszów reservoirs indicated a higher possibility of occurrence of an adverse ecological effect. PCA analysis found slight difference between the reservoirs in the profile of variable PAHs. Only the sediments from the Rybnik and Chechło reservoirs differ considerably from this grouping.

The article considered the influence the various types of land use on microbial activity of soils and thus using this parameter as a universal test of soil quality. Samples for soil respiration studies were taken from agricultural areas, meadows, forests and urban areas (estate cottages). All samples were subjected to the same analytical procedure and the method of measurement was followed by a Substrate-Induced Respiration (SIR) method. Since all the samples were from neighbouring regions and were characterized by similar soil parameters, the obtained results allowed to assess the quality of the soil environment of the surveyed area and to evaluate the total rating of whole area. The obtained results allowed to observe slight divergences between soil samples taken from areas of different use. And although statistically, in this case, these differences were not significant, the characteristics of the respiration curves clearly indicate that there is a dependency between the form of use and the size and rate of soil respiration. In addition, the results have shown that single family housing does not exhibit as much anthropopression to the soil environment as it might seem.

Forests are considered one of the most valuable natural areas in metropolitan region landscapes. Considering the sensitivity and ecosystem services provided by trees, the definition of urban forest ecosystems is nowadays based on a comprehensive understanding of the entire urban ecosystem. The effective capturing of particulate matter is one of the ecosystem services provided by urban forests. These ecosystems function as efficient biological filters. Plants accumulate pollutants passively via their leaves. Therefore, another ecosystem service provided by city forests could be the use of tree organs as bioindicators of pollution. This paper aims to estimate differences in trace metal pollution between the wooded urban areas of Vienna and Krakow using leaves of evergreen and deciduous trees as biomonitors. An additional objective of the research was to assess the ability of the applied tree species to act as biomonitors. Plant samples of five species—Norway spruce, Scots pine, European larch, common white birch, and common beech—were collected within both areas, in seven locations: four in the “Wienerwald” Vienna forest (Austria) and three in the “Las Wolski” forest in Krakow (Poland). Concentrations of Cr, Cu, Cd, Pb, and Zn in plant material were determined. Biomonitoring studies with deciduous and coniferous tree leaves showed statistically higher heavy metal contamination in the “Las Wolski” forest compared to the “Wienerwald” forest. Based on the conducted analyses and the literature study, it can be concluded that among the analyzed tree species, only two: European beech and common white birch can be considered potential indicators in environmental studies. These species appear to be suitable bioindicators, as both are widespread in urban woodlands of Central Europe and have shown the highest accumulation levels of trace metals.