In recent years, transitional metal sulfides have received much attention as lithium ion batteries (LIBs) anode. In this paper, FeS/C nanosheets are prepared through Fe-based metal organic frameworks (Fe-MOFs) as a precursor. The electrochemical performance of FeS/C nanosheets has been obviously improved due to the synergistic effect of the oxygen doped carbon and the special flake morphology. When the test current density is 0.1 A/g, the initial discharge capacities of FeS/C nanosheets is up to 1702 mAh/g and can retain reversible capacities of about 830 mAh/g over 150 cycles with the voltage ranging from 0.01 V to 3 V. Moreover, these composite materials are proved to have a good rate performance and the capacities reach 460 mAh/g even at a higher current density of 5 A/g. This work suggests that FeS/C nanosheets are excellent anode materials for LIBs.
Bismuth ferrite (BFO) nanoparticle with general formula Bi1-xNdxFe1-yCoyO3 (x=0, 0.05; y=0, 0.05, 0.10, 0.15, 0.20) were prepared using a two-solvent sol-gel method. Interestingly, most of the samples exhibited a cellular architecture. Bandgap engineering of BFO nanoparticles was achieved by co-doping with Nd and Co. Under illumination with ultraviolet light, the concentration of methylene orange increased. The sample of Bi0.95Nd0.05Fe0.85Co0.15O3 produced a small amount of hydrogen (8.88molg-1 after 1.5;h), but the other samples did not produce detectable levels of hydrogen. In this research, the production of hydrogen occurred under illumination by ultraviolet light, demonstrating the splitting of pure water without the use of a sacrificial reagent. A possible reason for this is that the conduction and valence band edges of BiFeO3 straddle the water redox potential. Consequently, it is possible to realize unassisted water splitting using BFO. The ferromagnetism of all samples increased linearly with the increase of dopant concentration, and the residual magnetization of the Bi0.95Nd0.05Fe0.80Co0.20O3 sample reached to 0.679 emu g−1. Moreover, the magnetic properties of bismuth ferrite and Nd/Co Co-doped bismuth ferrite photocatalyst were also investigated to show the simple separation. These results demonstrate that BFO nanoparticles have potential applications in photocatalytic hydrogen production without the use of a sacrificial reagent.