The morphology of bulk heterojunction organic photovoltaic cells controls many of the performance characteristics of devices. However, measuring this morphology is challenging because of the small length-scales and low contrast between organic materials. Here we use nanoscale photocurrent mapping, ultrafast fluorescence and exciton diffusion to observe the detailed morphology of a high-performance blend of PTB7:PC₇₁BM. We show that optimized blends consist of elongated fullerene-rich and polymer-rich fibre-like domains, which are 10–50 nm wide and 200–400 nm long. These elongated domains provide a concentration gradient for directional charge diffusion that helps in the extraction of charge pairs with 80% efficiency. In contrast, blends with agglomerated fullerene domains show a much lower efficiency of charge extraction of ~45%, which is attributed to poor electron and hole transport. Our results show that the formation of narrow and elongated domains is desirable for efficient bulk heterojunction solar cells.

Controlling the flux of photons is crucial in many areas of science and technology. Artificial materials with nano-scale modulation of the refractive index, such as photonic crystals, are able to exercise such control and have opened exciting new possibilities for light manipulation. An interesting alternative to such periodic structures is the class of materials known as quasi-crystals, which offer unique advantages such as richer Fourier spectra. Here we introduce a novel approach for designing such richer Fourier spectra, by using a periodic structure that allows us to control its Fourier components almost at will. Our approach is based on binary gratings, which makes the structures easy to replicate and to tailor towards specific applications. As an example, we show how these structures can be employed to achieve highly efficient broad-band light trapping in thin films that approach the theoretical (Lambertian) limit, a problem of crucial importance for photovoltaics.

Metalenses consist of nanostructures that locally control the optical phase. They offer many degrees of freedom for manipulating a wavefront, which gives a number of advantages over bulk lenses, such as the straightforward elimination of spherical aberrations and an ultrathin dimension. Here, we compare the phase profiles of metalenses made of different dielectric materials and note the advantage of high refractive index materials. Higher refractive index materials such as silicon afford more degrees of freedom in terms of design and fabrication and are the basis for high-performance metalenses, even in the visible. Nevertheless, the imaging performance of single-element metalenses is still limited by coma and chromatic aberrations. This limitation is exacerbated by high numerical apertures and large areas. We review the challenges and trade-offs between numerical aperture, field of view, coma, chromatic aberration, and size. We also evaluate different phase engineering approaches to address these problems. We believe this review will help guide future developments in high-performance metalenses toward wide-field and high-resolution imaging, enabling scientific high-end miniature imaging systems.

The question of the optimal surface structure for light trapping is widely debated in thin-film solar cell research. Here we propose a generic design approach that can tailor the strength of the diffraction orders of a periodic structure. Our approach is based on a supercell geometry that is able to suppress the low orders that do not couple into the quasiguided modes of the thin film. We demonstrate the concept theoretically and experimentally, showing that the supercell outperforms conventional gratings.

We demonstrate high aperture (up to $\mathrm{NA}\sim 0.64$) three-dimensional focusing in free space based on wavefront-engineered diffraction gratings. The grating lens’ optical response is tailored by spatially varying the grating ridge and groove width in two dimensions to achieve focal lengths of order 100 μm that are crucial for micro-optical applications. The phase profile of the lens includes multiple $2\pi$ phase jumps and was obtained by applying an algorithm for finding the optimal path for both phase and amplitude. Experimental measurements reveal a lateral spot size of 5 μm that is close to the size of a corresponding Airy disk.

S. Zhang, E.R. Martins, G.A. Turnbull and I.D.W. Samuel are grateful to the Scottish Universities Physics Alliance (SUPA) and the Engineering and Physical Sciences Research Council (EPSRC) for financial support.Integrating photonic microstructures into organic light-emitting diodes (OLEDs) has been a widely used strategy to improve their light out-coupling efficiency. However, there is still a need for optical modelling methods which quantitatively characterise the spatial emission pattern of microstructured OLEDs. In this paper, we demonstrate such rigorous calculation using the reciprocity theorem. The calculation of the emission intensity at each direction in the far field can be simplified into only two simple calculations of an incident plane wave propagating from the far field into a single cell of the periodic structure. The emission from microstructured OLED devices with three different grating periods was calculated as a test of the approach, and the calculated results were in good agreement with experiment. This optical modelling method is a useful calculation tool to investigate and control the spatial emission pattern of microstructured OLEDs.PostprintPeer reviewe