Alkali-activated materials (AAMs) are widely recognized as potential alternatives to ordinary Portland cement (OPC) due to their lower carbon footprint. However, like OPC, AAMs can also generate some durable problems when exposed to aggressive environments and the mechanisms and possible improvements are still not fully clear in existing investigations. Furthermore, the corrosion mechanisms of AAMs are different from OPC due to the discrepant reaction products and pore structures. Thus, this study’s aim is to review the chemical reaction mechanisms, factors, and mitigation methods when AAMs are attacked by carbonation and chloride ions, along with a summative discussion regarding instructive insights to durable problems of AAMs.
Wearable triboelectric nanogenerators (TENGs) have attracted interest in recent years, which demand highly flexible, scalable, and low-cost features. Here, we report an ultra-flexible, large-scale and textile-based TENG (T-TENG) for scavenging human motion energy. The triboelectric layer was derived from the polydimethylsiloxane (PDMS) film with a cost-effective paper-induced rough surface via a facile doctor-blending technology. Ag-coated chinlon fabric (ACF) with ultra-flexible, large-scale and conductive characteristics was used as the electrode. The as-fabricated PDMS-based ACF (PACF) composites possess a 240 × 300 mm2 superficial area and remain highly flexible under mechanical squeezing, folding and even tearing deformation. The maximum output charge of ~21 μC and voltage of 80.40 V were therefore achieved to directly power 100 LEDs based on the high surface area of 762.73 mm2 which was rationally replicated from the sandpaper of the T-TENG. Moreover, the output voltage signal can be also used as a trigger signal of a movement sensor. Importantly, the explicit theoretical model corresponding to T-TENG was quantitatively investigated under different applied force, frequency and effective surface factor.
The influence of fiber volume content on the mechanical properties of two-dimensional (2D) plain carbon-fiber woven composites is a crucial concern that necessitates immediate attention for large-scale applications in wind turbine blades. In this study, various mechanical tests were conducted on 2D plain carbon-fiber woven composites with different fiber volume contents, and the influences of fiber volume content on the mechanical properties and failure mode of the composite material were analyzed. Using carbon fiber as reinforcement and epoxy resin as a matrix, three types of plates with fiber volume contents of 47%, 50% and 53% were fabricated by using autoclave technology. The tensile, compression and interlaminar shear tests of the two-dimensional woven composites were carried out using MTS series testing machines. The influences of fiber volume content on tensile strength and modulus, compressive strength and modulus, interlaminar shear strength and shear strain energy were investigated. Additionally, the progressive damage development of these two-dimensional woven composites under different stress states was studied using scanning electron microscopy (SEM). The results indicate that the tensile strength and compressive strength increase almost linearly with the increase in fiber volume content, while the interlaminar shear strength increases slowly at low fiber volume content and rapidly at high fiber volume content. The tensile modulus of elasticity slightly increases as the fiber volume content increases, whereas the compressive modulus remains stable at low fiber volume content but gradually decreases at high fiber volume content. With the increase in fiber volume content, the shear strain energy of the specimen increases significantly.
1 July 2019 in Journal of Wind Engineering and Industrial Aerodynamics
Calcium leaching is a degradation progress inside hardened cement composites, where Ca2+ ions in cement pore solution can migrate into the aggressive solution. In this work, calcium leaching of graphene oxide (GO) reinforced cement composites was effectively characterized by combined techniques of electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM). Inhibiting mechanism of GO on calcium leaching of the composites was also examined. The obtained results show that the diameter of the semi-circle of the Nyquist curves of leached samples with GO addition decreased less than that of controlled samples. After leaching for 35 days, loss rate of model impedance RCCP of leached samples with 0, 0.05, 0.1, 0.15, and 0.2 wt.% GO addition was 94.85%, 84.07%, 79.66%, 75.34%, and 68.75%, respectively. Therefore, GO addition can significantly mitigate calcium leaching of cement composites, since it can absorb Ca2+ ions in cement pore solution, as well as improve the microstructure of the composites. In addition, coupling leaching depth and compressive strength loss were accurately predicted by using the impedance RCCP.