In saline soil and alpine regions of northwest China, fiber-reinforced recycled aggregate concrete (FR-RAC) beams are subjected to coupled degradation from a chloride–sulfate composite salt attack and freeze–thaw cycling. Existing studies predominantly focus on natural aggregate concrete in freshwater environments or single-salt solutions, with limited documentation on the shear performance of FR-RAC beams after freeze–thaw exposure in chloride–sulfate composite salt solutions. To investigate the durability degradation patterns of FR-RAC beams in Xinjiang’s saline soil regions, two exposure environments (pure water and 5% NaCl + 2.0% Na₂SO₄ composite salt solution) were established. Shear performance tests were conducted on nine groups of FR-RAC beams after 0–175 freeze–thaw cycles, with measurements focusing on failure modes, cracking loads, and ultimate shear capacities. The results revealed that under composite salt freeze–thaw conditions: after 100 cycles, the cracking load and shear capacity of tested beams decreased by 39.8% and 22.2%, respectively, compared to unfrozen specimens representing reductions 29.6% and 82.0% greater than those in freshwater environments; at 175 cycles, cumulative damage intensified, with total reductions reaching 56.8% (cracking load) and 36.1% (shear capacity). A shear capacity degradation prediction model for FR-RAC beams under composite salt freeze–thaw coupling was developed, accounting for concrete strength attenuation and interfacial bond degradation. Model validation demonstrated excellent agreement between predicted and experimental values, confirming its robust applicability.

With global sustainable construction growth, fully recycled coarse aggregate concrete (RCAC)—eco-friendly for cutting construction waste and reducing natural aggregate over-exploitation—has poor durability in seasonally freezing saline-soil regions (e.g., Tumushuke, Xinjiang): freeze-thaw and salt ions (NaCl, Na₂SO₄) cause microcracking, faster performance decline, and shorter service life, limiting its use and requiring better salt freeze resistance. To address this, a field survey of Tumushuke’s saline soil was first conducted to determine local salt type and concentration, based on which a matching 12% NaCl + 4% Na₂SO₄ mixed salt solution was prepared. RCAC specimens modified with fly ash (FA), silica fume (SF), and polypropylene fiber (PPF) were then fabricated, cured under standard conditions (20 ± 2 °C, ≥95% relative humidity), and subjected to rapid freeze-thaw cycling in the salt solution. Multiple macro-performance and microstructural indicators (appearance, mass loss, relative dynamic elastic modulus (RDEM), porosity, microcracks, and corrosion products) were measured post-cycling. Results showed the mixed salt solution significantly exacerbated RCAC’s freeze-thaw damage, with degradation severity linked to cycle count and admixture dosage. The RCAC modified with 20% FA and 0.9% PPF exhibited optimal salt freeze resistance: after 125 cycles, its RDEM retention reached 75.98% (6.60% higher than the control), mass loss was only 0.28% (67.80% lower than the control), and its durability threshold (RDEM > 60%) extended to 200 cycles. Mechanistic analysis revealed two synergistic effects for improved performance: (1) FA optimized pore structure by filling capillaries, reducing space for pore water freezing and salt penetration; (2) PPF enhanced crack resistance by bridging microcracks, suppressing crack initiation/propagation from freeze-thaw expansion and salt crystallization. A “pore optimization–ion blocking–fiber crack resistance” triple synergistic protection model was proposed, which clarifies admixture-modified RCAC’s salt freeze damage mechanism and provides theoretical/technical guidance for its application in extreme seasonally freezing saline-soil environments.