Hydrogels, especially Polyvinyl alcohols, have received extensive attention as alternative materials for articular cartilage. Aiming at the problems such as low strength and poor toughness of polyvinyl alcohol hydrogels in practical applications, an enhancement and modification strategy is proposed. Sodium alginate fibers were introduced into polyvinyl alcohol hydrogel network through physical blending and freezing/thawing methods. The prepared composite hydrogels exhibited a three-dimensional porous network structure similar to that of human articular cartilage. The mechanical and tribological properties of hydrogels have been significantly improved, due to the multiple hydrogen bonding interaction between sodium alginate fibers and polyvinyl alcohol. Most importantly, under a load of 2 N, the friction coefficient of the PVA/0.4SA hydrogel can remain stable at 0.02 when lubricated in PBS buffer for 1 h. This work provides a novel design strategy for the development of high-performance polyvinyl alcohol hydrogels.
The (1−x)Ba0.96Ca0.04TiO3−xBi(Li1/3Zr2/3)O3 (x = 0.03–0.15) ceramics were fabricated via the traditional solid reaction method. Characterization results revealed that each component exhibited a pure perovskite structure, and the average grain size significantly diminishes with increasing x. The (1−x)Ba0.96Ca0.04TiO3−xBi(Li1/3Zr2/3)O3 ceramics exhibited prominent relaxor ferroelectric behavior, whose characteristic narrow hysteresis loops effectively enhanced the energy storage performance of the material. Most importantly, the composition with x = 0.10 demonstrated exceptional energy storage properties at 150 kV/cm, achieving a high recoverable energy storage density (Wrec = 1.91 J/cm3) and excellent energy efficiency (η = 90.87%). Under the equivalent electric field, this composition also displayed a superior pulsed discharge performance, including a high current density (871 A/cm2), a high power density (67.3 MW/cm3), an ultrafast discharge time (t0.9 = 109 ns), and a discharged energy density of 1.47 J/cm3. These results demonstrate that the (1−x)Ba0.96Ca0.04TiO3−xBi(Li1/3Zr2/3)O3 ceramic system establishes a promising design paradigm for the creation and refinement of next-generation dielectrics for pulse power applications.
Traditional artificial joints mainly face the challenges of severe wear and aseptic loosening, which limits their application as joint bearing interfaces under high-stress loading conditions. To improve this problem, inspired by the gradient modulus structure of natural cartilage/subchondral bone and the inherent negative charge characteristics of the surface, a negatively charged hydrogel layer was adhered to a porous Ti6Al4V surface through a combination of ultraviolet irradiation and freeze–thaw cycles. The cross-sectional SEM image exhibited that the hydrogel layer was closely bonded to the hard substrate. After physical doping with SBMA, the lubrication performance of the composite bearing interface was significantly improved, primarily attributable to the biphasic lubrication of the hydrogel layer and the hydration lubrication mechanism of SBMA.