The industrial objective of lowering the mass of mechanical structures requires continuous improvement in controlling the mechanical properties of metallic materials. Steel cleanliness and especially control of inclusion size distribution have, therefore, become major challenges. Inclusions have a detrimental effect on fatigue that strongly depends both on inclusion content and on the size of the largest inclusions. Ladle treatment of liquid steel has long been recognized as the processing stage responsible for the inclusion of cleanliness. A multiscale modeling has been proposed to investigate the inclusion behavior. The evolution of the inclusion size distribution is simulated at the process scale due to coupling a computational fluid dynamics calculation with a population balance method integrating all mechanisms, i.e., flotation, aggregation, settling, and capture at the top layer. Particular attention has been paid to the aggregation mechanism and the simulations at an inclusion scale with fully resolved inclusions that represent hydrodynamic conditions of the ladle, which have been specifically developed. Simulations of an industrial-type ladle highlight that inclusion cleanliness is mainly ruled by aggregation. Quantitative knowledge of aggregation kinetics has been extracted and captured from mesoscale simulations. Aggregation efficiency has been observed to drop drastically when increasing the particle size ratio.
22 October 2013 in Metallurgical and Materials Transactions B
During the processing of maraging steels, Titanium easily combines with Nitrogen to form nitride inclusions, known to be deleterious for fatigue properties of the alloy. According to thermodynamic calculations, the precipitation occurs during solidification of the vacuum arc remelted (VAR) ingot. A coupled model of titanium nitride (TiN) inclusion precipitation and vacuum remelting has been set-up to study the inclusion cleanliness of the ingot. The nitrogen content, nuclei numeral density and solidification time appear as the key factors which control the inclusion size.