Transparent electrodes (TEs) made of metallic nanowires, such as Ag, Au, Cu, and Ni, are attracting increasing attention for several reasons: (1) they can act as a substitute for tin oxide-based TEs such as indium-tin oxide (ITO) and fluorine-doped tin oxide (FTO); (2) various methods exist for fabricating such TEs such as filtration, spraying, and Meyer bar coating; (3) greater compatibility with different substrates can be achieved due to the variety of fabrication methods; and (4) extra functions in addition to serving as electrodes, such as catalytic abilities, can be obtained due to the metals of which the TEs are composed. There are a large number of applications for TEs, ranging from electronics and sensors to biomedical devices. This short review is a summary of recent progress, mainly over the past five years, on silver nanowire-based TEs. The focus of the review is on theory development, mechanical, chemical, and thermal stability as well as optical properties. The many applications of TEs are outside the scope of this review.
In this work we present experimental evidence that the valence instability of the ytterbium ion play a key role for the observed photodarkening mechanism in Yb-doped fiber lasers. Luminescence and excitation spectroscopy performed on UV irradiated Yb/Al doped silica glass preforms and near-infrared diode pumped photodarkened fibers show a concentration increase of Yb2+ ions. A concentration decrease in Yb3+ could also be observed for the UV irradiated preform. The findings contribute to an increased understanding of the kinetic processes related to photodarkening in Yb-doped high power fiber lasers.
We report what we believe to be the first radiation-balanced fiber amplifier—a device that provides optical gain while experiencing no temperature rise. The gain medium is a silica fiber with a -diameter core highly doped with (2.52 wt. %) and codoped with 2.00 wt. % Al to reduce concentration quenching. The amplifier is core pumped with 1040-nm light to create anti-Stokes fluorescence cooling and gain in the core at 1064 nm. Using a custom slow-light fiber Bragg grating sensor with mK resolution, temperature measurements are performed at multiple locations along the amplifier fiber. A 4.35-m fiber pumped with 2.62 W produced 17 dB of gain, while the average fiber temperature remained slightly below room temperature. This advancement is a fundamental step toward the creation of ultrastable lasers necessary to many applications, especially low-noise sensing and high-precision metrology.
In optically pumped lasers, heat generated by the quantum defect causes detrimental fluctuations in the output mode, frequency, and power. Common heat-mitigation techniques use bulky mechanical coolers that introduce vibrations, leading to laser frequency and amplitude noise. Here, we present a radiation-balanced fiber laser, optically cooled by anti-Stokes fluorescence (ASF). The gain medium is a silica fiber with a 21-µm-diameter core doped with 2.06 wt. % and co-doped with and F- to reduce concentration quenching. The laser was core-pumped at 1040 nm to create both gain at 1065 nm and ASF cooling at atmospheric pressure. We demonstrate a maximum output power of 114 mW with a slope efficiency of 41% while maintaining near-zero average temperature change. This result could enable the development of fiber lasers with unprecedented coherence and stability.
5 October 2021 in Journal of the Optical Society of America B
The performance of optical fibers is dependent on both the fiber design and the materials from which it is made. While much of the development over the past few decades has focused on fiber geometry and microstructuring, more recent analyses have shown clear benefits of addressing parasitic nonlinearities at the origins of their light–matter interactions. Reported here are results on intrinsically low Brillouin and thermo-optic core fibers, fabricated using modified chemical vapor deposition. Specifically, fibers in the Yb-doped system are developed based on how each glass constituent affects the material parameters that enable both stimulated Brillouin scattering (SBS) and transverse mode instability (TMI). One fiber, developed to be very heavily doped, exhibited thermo-optic and Brillouin gain coefficients up to and 6 dB below conventional laser fibers, respectively. A second fiber, designed to approximate a commercial double-clad laser fiber, which necessitated lower doping levels, was output power scaled to over 1 kW with an efficiency over 70% and no observed photodarkening under conventional testing. Design curves for the enabling material properties that drive TMI and SBS also are provided as functions of compositions as a tool for the community to further study and develop intrinsically low-nonlinearity fiber lasers.
The first observation of cooling by anti-Stokes pumping in nanoparticle-doped silica fibers is reported. Four Yb-doped fibers fabricated using conventional modified chemical vapor deposition (MCVD) techniques were evaluated, namely, an aluminosilicate fiber and three fibers in which the Yb ions were encapsulated in CaF2, SrF2, or BaF2 nanoparticles. The nanoparticles, which oxidize during preform processing, provide a modified chemical environment for the Yb3+ ions that is beneficial to cooling. When pumped at the near-optimum cooling wavelength of 1040 nm at atmospheric pressure, the fibers experienced a maximum measured temperature drop of 20.5 mK (aluminosilicate fiber), 26.2 mK (CaF2 fiber), and 16.7 mK (SrF2 fiber). The BaF2 fiber did not cool but warmed slightly. The three fibers that cooled had a cooling efficiency comparable to that of the best previously reported Yb-doped silica fiber that cooled. Data analysis shows that this efficiency is explained by the fibers’ high critical quenching concentration and low residual absorptive loss (linked to sub-ppm OH contamination). This study demonstrates the large untapped potential of nanoparticle doping in the current search for silicate compositions that produce optimum anti-Stokes cooling.