In tight oil reservoirs, water imbibition is the key mechanism to improve oil production during shut-in operations. However, the complex microstructure and composition of minerals complicate the interpretation of oil migration during water imbibition. In this study, nuclear magnetic resonance (NMR) T2 spectra was used to monitor the oil migration dynamics in tight oil reservoirs. The factors influencing pore size distribution, micro-fractures, and clay minerals were systematically investigated. The results show that the small pores corresponded to a larger capillary pressure and a stronger imbibition capacity, expelling the oil into the large pores. The small pores had a more effective oil recovery than the large pores. As the soaking time increases, the water preferentially entered the natural micro-fractures, expelling the oil in the micro-fractures. Subsequently, the oil in the small pores was slowly expelled. Compared with the matrix pores, natural micro-fractures had a smaller flow resistance and were more conducive to water and oil flow. Clay minerals may have induced micro-fracture propagation, which can act as the oil migration channels during water imbibition. In contrary to the inhibitory effect of natural micro-fractures, the new micro-fractures could contribute to the oil migration from small pores into large pores. This study characterized the oil migration characteristics and provides new insight into tight oil production.
Drilling fluid losses into formation voids are among the major issues that lead to increases in the costs and nonproductive time of operations. Lost circulation materials have been widely used to stop or mitigate losses. In most cases, the size of the loss zone is not known, making conventional lost circulation materials unsuitable for plugging the loss zone. In this study, novel temperature-sensitive LCM (TS-LCM) particles composed of diglycidyl ether of bisphenol A (DGEBA) and 4,4′-diaminodiphenyl methane were prepared. It is a thermal-response shape-memory polymer. The molecular structure was analyzed by Fourier transform infrared spectroscopy. The glass transition temperature (Tg) was tested by Different scanning calorimetry (DSC). The shape-memory properties were evaluated by a bend-recovery test instrument. The expansion and mechanical properties of particles were investigated under high temperature and high pressure. Fracture sealing testing apparatus was used to evaluate sealing performance. The mechanism of sealing fracture was discussed. Research results indicated that the Tg of the TS-LCM was 70.24 °C. The shape fixation ratio was more than 99% at room temperature, and the shape recovery ratio was 100% above the Tg. The particle was flaky before activation. It expanded to a cube shape, and the thickness increased when activated. The rate of particle size increase for D90 was more than 60% under 120 °C and 20 MPa. The activated TS-LCM particles had high crush strength. The expansion of the TS-LCM particles could self-adaptively bridge and seal the fracture without knowing the width. The addition of TS-LCM particles could seal the tapered slot with entrance widths of 2 mm, 3 mm and 4 mm without changing the lost circulation material formulation. The developed TS-LCM has good compatibility with local saltwater-based drilling fluid. In field tests in the Yan’an area of the Ordos Basin, 15 shale oil horizontal wells were plugged with excellent results. The equivalent circulating density of drilling fluid leakage increased by an average of 0.35 g/cm3, and the success rate of plugging malignant leakage increased from 32% to 82.5%. The drilling cycle was shortened by an average of 14.3%, and the effect of enhancing the pressure-bearing capacity of the well wall was significant. The prepared TS-LCM could cure fluid loss in a fractured formation efficiently. It has good prospects for promotion.
This study introduces a novel organosilicon-modified polysaccharide (Si-AP) synthesized via grafting and comprehensively evaluates its performance in water-based drilling fluids (WBDFs). The molecular structure of Si-AP was characterized using Fourier-transform infrared spectroscopy (FTIR) and 1H-NMR experiments. Thermalgravimetric analysis (TGA) confirmed the good thermal stability of Si-AP up to 235 °C. Si-AP significantly improves the rheological properties and fluid loss performance of WBDFs. With increasing Si-AP concentration, system viscosity increases, API filtration rate decreases, clay expansion is inhibited, and drilling cuttings hydration dispersion is suppressed, especially under high-temperature conditions. Additionally, mechanistic analysis indicates that the introduction of siloxane groups can effectively inhibit the thermal degradation of AP chains and enhance their high-temperature resistance. Si-AP can form a lubricating film by adsorbing on the surface of clay particles, improving mud cake quality, reducing the friction coefficient, and significantly enhancing the lubricating performance of WBDFs. Overall, Si-AP exhibits a higher temperature-resistance limit compared to AP and more effectively optimizes the lubrication, inhibition, and control of the filtration rate of WBDFs under high-temperature conditions. While meeting the requirements of drilling fluid systems under high temperatures, Si-AP also addresses environmental concerns and holds promise as an efficient solution for the exploitation of deep-seated oil and gas resources.