Micro-cracks and material deterioration occur in concrete under high-temperature conditions. To reveal the impact resistance of concrete at a high temperature, a dynamic splitting test and dynamic compression test were carried out using a split Hopkinson pressure bar (SHPB). The failure process and dynamic stress–strain curve of the concrete specimens were obtained, investigating the failure mode and dynamic tensile and compressive strength of the concrete. The test results showed that the surface cracks appeared along the loading direction and extended to the core area under the impact load. With an increase in the temperature, different degrees of damage would be caused, the dynamic strength and toughness of the concrete would decrease, showing brittle failure, and the energy absorbed in the failure process would also decrease correspondingly.

Concrete used in high-risk infrastructures must withstand elevated temperatures and thermal shocks. This study investigated the thermal transfer behavior of explosion-proof concrete exposed to 100–400 °C through a combined experimental and numerical approach. X-ray diffraction (XRD) revealed that the dominant crystalline phases remained identifiable across this range, but peak broadening and intensity reduction indicated partial decomposition of hydration products and microstructural disorder. Thermal conductivity reached its maximum of 1.48 W/(m·K) at 100 °C and decreased at higher temperatures due to porosity growth and microcracking, reflecting detrimental alterations in heat conduction pathways. In contrast, the specific heat capacity increased from 963.89 J/(kg·K) at 100 °C to 1122.22 J/(kg·K) at 400 °C, enhancing the material’s heat absorption. Density initially decreased with temperature but showed a temporary rebound at 300 °C due to secondary hydration, before dropping sharply to 1830 kg/m³ at 400 °C. Numerical simulations confirmed that high temperatures reduce surface–core temperature gradients, leading to more uniform but structurally weakened heat transfer. These findings highlight that explosion-proof concrete retains acceptable thermal stability below 200 °C, while significant degradation occurs beyond 300 °C. The novelty of this work lies in integrating experimental thermophysical tests with finite element simulations to link microstructural changes with macroscopic thermal behavior. Practically, the results provide guidance for optimizing concrete formulations and protective strategies in fire- and explosion-prone facilities such as LNG storage units and petrochemical infrastructures.