This study focuses on the power systems of inland waterway vessels in Chinese Yangtze River, systematically outlining the low-carbon technology pathways for different power system types. A comparative analysis is conducted on the technical feasibility, emission reduction potential, and economic viability of LNG, methanol, ammonia, pure electric and hybrid power systems, revealing the bottlenecks hindering the large-scale application of each system. Key findings indicate that: (1) LNG and methanol fuels offer significant short-term emission reductions in internal combustion engine power systems, yet face constraints from methane slip and insufficient green methanol production capacity, respectively; (2) ammonia enables zero-carbon operations but requires breakthroughs in combustion stability and synergistic control of NOX; (3) electric vessels show high decarbonization potential, but battery energy density limits their range, while PEMFC lifespan constraints and SOFC thermal management deficiencies impede commercialization; (4) hybrid/range-extended power systems, with superior energy efficiency and lower retrofitting costs, serve as transitional solutions for existing vessels, though challenged by inadequate energy management strategies and multi-equipment communication protocol interoperability. A phased transition pathway is proposed: LNG/methanol engines and hybrid systems dominate during 2025–2030; ammonia-powered systems and solid-state batteries scale during 2030–2035; post-2035 operations achieve zero-carbon shipping via green hydrogen/ammonia.
Layered Li-rich manganese-based Li1.2Ni0.13Co0.13Mn0.54O2 (LNCMO) is regarded as a promising high-capacity cathode material. However, its commercial application is severely hindered by rapid capacity fading, serious voltage decay and poor cycling stability. Herein, a facile non-sintering electrostatic adsorption strategy employing PDDA is proposed to fabricate a uniform and dense graphene oxide (GO) coating on LNCMO particles. Structural and morphological characterizations confirm the successful decoration of GO on the surface of LNCMO. The optimized 0.5@LNCMO sample delivers a discharge capacity of 330 mAh g−1 at 0.1C, and maintains a capacity retention of 86.5% after 200 cycles at 1C and 83.3% after 400 cycles at 5C, showing much better electrochemical performance than pristine LNCMO. This study proves that the proposed strategy is an effective modification method for constructing high-performance Li-rich cathode materials.