The effects of irradiation by a corona glow discharge plasma on hidrophylicity properties of polyester and cotton fabrics were investigated. We used a corona glow discharge plasma reactor with multiple points to plane electrodes, which was generated by a high voltage DC. Factors that affect the hidrophylicity properties were identified and evaluated as functions of irradiation parameters, which include duration of treatment, distance between electrodes, and bias voltage. It was readily observed from SEM examinations that plasma changed the surface morphology of both polyester and cotton fibers, giving result to an increased roughness to both of them. Results also showed that the hidrophylicityof polyester and cotton fabrics improved by the treatment, which is proportional to the time of treatment and voltage, but inversely proportional to the distance between electrodes. Time of treatment that provided the optimum enhancement of hidrophylicity for cotton is 15 minutes which improved the wetting time from 8.16 seconds to 1.26 seconds. For polyester, it took 15 minutes of irradiation time to improve the wetting time from 7340 seconds to 2905 seconds. The optimum distance between electrodes for both fabrics in this study was found to be 2 cm. Further analysis showed that the improved hidrophylicity properties is due to the creation of surface radicals by free radicals in the plasma leading to the formation of new water-attracting functional groups on the fiber surface.
15 October 2019 in The Journal of the Textile Institute
Comfort has been one of the most important features of clothing, particularly for sportswear, which requires an effective transport of heat and moisture from the inner to the outer side of clothing. We herein report the use of a simple technique of spray coating and commercially available water repellents for a one-sided hydrophobic and self-initiated one-way water transport cotton fabric. The highlight of this work is the simplicity of the process and choice of chemicals that can be adopted easily by any textile finishing industry. On this fabric, water was able to diffuse and penetrate the fabric structure in one direction from the hydrophobic to the hydrophilic side but was unable to go the opposite direction. The directional transport improved with smaller droplets and lower add-on achievable by higher air pressure and longer distance of spray coating. From moisture management tests, the best result was obtained with the spray coating of Phobol NB-NH at an air pressure of 3.0 kgf/cm2 and a distance of 120 cm. Phobol NB-NH gave better result of transport and overall comfort properties than Phobotex RSY.
Unusual noisy discharge profiles were observed from some of our textile-based energy storage devices having asymmetrical electrodes consisting of pure stainless steel and silver-coated polybenzoxazole yarns. Our hypothesis was that it was due to the ionic shot noise behavior that occurred in electrochemical devices and is a well-known phenomenon in electronic devices. The poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) polymer coverage on the cell surface, which functioned as a solid electrolyte in this system, was believed to play an important role. To confirm this assumption, devices made with different drop-coating strategies to obtain thin and thick layers of PEDOT:PSS polymer on the cell surface were prepared. The noisy discharge profiles were observed from devices with thin polymer layers, while those with thick layers exhibited normal discharge profiles. The morphology of cell surfaces was characterized by a stereo microscope. Cross-section analysis of a device with a thick layer was employed to further characterize its film formation and elemental properties using Scanning Electron Microscopy-Electron Dispersive Spectroscopy. Formation of multilayers of PEDOT:PSS polymer on the cell surface allowed a continuous interaction between electrode metals and PEDOT:PSS ions at the interface area. The noisy component was caused by the movement of silver ions hopping from one trap to the next. A qualitative model of the autocorrelation function executed to the data with noisy behavior further confirmed the ionic shot noise phenomenon.
Strobilanthes cusia is one of many indigo-producing plants with promising and attractive potentials as an alternative source of natural indigo dye due to its dyeability to cotton fibres with high colour strength, and due to its ease of cultivation. The aim of this research was to utilise natural indigo dye from Strobilanthes cusia to dye cotton denim fabric in an environmentally friendly way. The use of D-fructose and D-glucose as well as rice husk ash and lime solutions as reducing agents and alkali sources was explored in this study. The dyeing process was carried out at 30 °C for 30 minutes, followed by the oxidation process in open air for 45 minutes. Colour characteristics and fastness to washing and rubbing were evaluated. The results showed that D-fructose resulted in a higher colour strength than D-glucose, and that lime is better than rice husk ash and even sodium hydroxide in terms of colour strength. The highest colour strength was obtained from the combination of D-fructose and lime solution, with K/S and SUM(K/S) values of 16.02 (at 650 nm) and 8.5 respectively. The colour fastness to washing and rubbing was good for all dyed fabrics, with the staining scale ranging from 3/4 to 4. These results bring a new potential for natural indigo dye from Strobilanthes cusia beyond its current and limited use by traditional dyers to a much larger scale of denim dyeing for an eco-friendly fashion industry.