The morphologies and local electronic structures of titanium coatings deposited on the surfaces of highly oriented pyrolytic graphite were determined. Chemical compositions of the oxides formed on the coating surfaces were established. A theoretical model was developed describing the changes in the TiO_x oxides (1.75 < x < 2) band gap depending on the duration and temperature of the titanium film annealing procedure in oxygen. The effective activation energy of oxygen diffusion in TiO_x (1.75 < x < 2) was determined, and the pre-exponential factor of the diffusion coefficient was estimated.

An experimental study of molecular hydrogen adsorption on single gold nanoparticles of various sizes deposited on the surface of highly oriented pyrolytic graphite (HOPG) was carried out by means of scanning tunneling microscopy and spectroscopy. The effect of size on the HOPG/Au system was established. Hydrogen was dissociatively chemisorbed on the surface of gold nanoparticles with an average size of 5–6 nanometers. An increase in the size of nanoparticles to 10 nm or more led to hydrogen chemisorption being inhibited and unable to be detected.

The oxidation of Ni nanoparticles supported on highly oriented pyrolytic graphite was investigated under conditions of low exposure to oxygen by methods of scanning tunneling microscopy and spectroscopy. It was found that charge transfer effects at the Ni-C interface influenced the surface activity of the nanoparticles. The O₂ dissociation and the Ni oxidation were shown to occur only at the top of the nanoparticle, while the border of the Ni-C interface was the less preferable area for these processes. The O₂ dissociation was inhibited, and atomic oxygen diffusion was suppressed in the given nanosystem, due to the decrease in holes concentration.

The hydrogenation features of gold nanoparticles deposited on highly oriented pyrolytic graphite were determined, and composite nanostructures consisting of pure and hydrogenized gold were synthesized. Methods of scanning tunneling microscopy and spectroscopy have been successfully used to probe the bottom of the conductive band and to determine the shape of the electron energy barrier in hydrogenized gold. Considering models of surface and volume hydrogenation, we have shown that no hydrogen dissolution occurred in gold nanoparticles, but all changes in their electronic structure were associated with surface processes. The results of the quantum chemical simulation also corresponded with this conclusion.

In this work, we studied the local adsorption properties of gold, nickel, and platinum nanoparticles. A correlation was established between the chemical properties of massive and nanosized particles of these metals. The formation of a stable adsorption complex M-A_ads on the nanoparticles’ surface was described. It was shown that the difference in local adsorption properties is caused by specific contributions of nanoparticle charging, the deformation of its atomic lattice near the M–C interface, and the hybridization of the surface s- and p-states. The contribution of each factor to the formation of the M-A_ads chemical bond was described in terms of the Newns–Anderson chemisorption model.

Microcrystalline cellulose (MCC) is a chemically pure product of cellulose mechano-chemical conversion. It is a white powder composed of the short fragments of the plant cells widely used in the modern food industry and pharmaceutics. The acid hydrolysis of the bleached lignin-free cellulose raw is the main and necessary stage of MCC production. For this reason, the acid hydrolysis is generally accepted to be the driving force of the fragmentation of the initial cellulose fibers into MCC particles. However, the low sensibility of the MCC properties to repeating the hydrolysis forces doubting this point of view. The sharp, cleave-looking edges of the MCC particles suggesting the initial cellulose fibers were fractured; hence the hydrolysis made them brittle. Zhurkov showed that mechanical stress decreases the activation energy of the polymer fracture, which correlates with the elevated enthalpy of the MCC thermal destruction compared to the initial cellulose.