Plant urease has the advantages of high activity and small size in enzyme-induced calcium carbonate precipitation (EICP). However, there area lack of nucleation sites for calcium carbonate in EICP. Sucrose and sorbitol, which are readily available and inexpensive, have the potential to provide nucleation sites for EICP as nucleating agents. To explore the effects of the two nucleating agents on EICP, the productivity of calcium carbonate, unconfined compressive strength (UCS) and microscopic mechanisms were tested. It is found that the productivity of EICP can be increased as much as 5.1% by the addition of sorbitol with an optimal content of 5%, and the productivity of EICP can be increased as much as 12.3% by the addition of sucrose with an optimal of 4%. The UCS of EICP-treated sand increases by 2.2 times after being improved by sorbitol with a content of 5.2%, the CaCO3 content of EICP-treated sand with sorbitol added increased by 1.5% compared to conventional EICP-treated sand. These results show that the two nucleating agents are effective for improving EICP. The SEM images verify that sorbitol/sucrose can compensate for the lack of nucleating sites in EICP and explicate the effect of nucleating agents on EICP.
Microbial-induced calcite precipitation (MICP) has gained much attention in soil improvement studies, where it can enhance the physical properties of sandy soil. Small-scale sand cylinder tests were conducted to investigate the formation and failure of calcium carbonate precipitation bonding between individual sand particles. Bonding formation by precipitation was examined by scanning electron microscopy. Energy-dispersive X-ray spectroscopy analysis verified the existence of calcium, carbon, and oxygen, which could form CaCO3 after MICP-treatment. Focused-ion-beam milling was applied to study the interior structure of calcium carbonate precipitation during the MICP process.
19 February 2024 in Construction and Building Materials
The unloading creep behavior of soft soil under lateral unloading stress path and excess pore water pressure is the core problem of time‐dependent analysis of surrounding rock deformation under excavation of soft soil. The soft soil in Shenzhen, China, was selected in this study. The triaxial unloading creep tests of soft soil under different initial excess pore water pressures (0, 20, 40, and 60 kPa) were conducted with the K0 consolidation and lateral unloading stress paths. The results show that the unloading creep of soft soil was divided into three stages: attenuation creep, constant velocity creep, and accelerated creep. The duration of creep failure is approximately 5 to 30 mins. The unloading creep behavior of soft soil is significantly affected by the deviatoric stress and time. The nonlinearity of unloading creep of soft soil is gradually enhanced with the increase of the deviatoric stress and time. The initial excess pore water pressure has an obvious weakening effect on the unloading creep of soft soil. Under the same deviatoric stress, the unloading creep of soft soil is more significant with the increase of initial excess pore water pressure. Under undrained conditions, the excess pore water pressure generally decreases during the lateral unloading process and drops sharply at the moment of unloading creep damage. The pore water pressure coefficients during the unloading process were 0.73–1.16, 0.26–1.08, and 0.35–0.96, respectively, corresponding to the initial excess pore water pressures of 20, 40, and 60 kPa.
28 June 2023 in International Journal of Civil Engineering