Lead-shielding products, such as lead aprons, are important materials for personal protection of physicians and patients from X-ray radiation during medical operations. However, lead has environmental disadvantages, with high toxicity. The aim of this study was to manufacture an environmentally friendly and flexible textile-based radiation shielding material. Tungsten, bismuth and barium sulfate powders were used as alternatives to lead with recognized shielding abilities against X-rays. The cotton fabrics were coated with silicone rubber that contains tungsten, bismuth or barium sulfate powders in equal weight fractions. X-ray attenuation ratios of the samples were measured at 80, 100 and 150 kV tube voltages in accordance with medical protection standards. Using the theoretical models, the thicknesses required for 90%, 95% and 99% attenuation ratios at the 100 kV energy level were also estimated for all the materials. The results showed that, at 60% weight ratio, 1.55 mm bismuth embedded coating can attenuate 90% of X-ray photons at the 100 kV level, while the required thickness of a tungsten embedded coating is 1.73 mm for the same protection level. At the same weight ratios the bismuth–silicone rubber blend reached better attenuation ratios per thickness in comparison with tungsten and barium sulfate powder–silicone rubber blends.

In this paper, tungsten, bismuth, tin, and copper powders were used as additives in the fabric coating to obtain lead-free and flexible x-ray shielding material. The X-ray attenuation and the flexural properties of the coated fabrics were investigated considering the medical protection requirements. The results showed that tungsten additives in silicone rubber coating had better attenuation ratios than the samples that contain tungsten–tin, bismuth, and tungsten–copper, at same additive volume ratios. Moreover, the increment of tungsten volume ratios in coating blend resulted in higher shielding performance at same effective thicknesses and the lower silicone rubber amount in coating lead to compose thinner and lighter fabrics for equal protection level. In addition to that, the samples with tungsten–tin, bismuth, and tungsten–copper showed remarkable attenuation properties, and the results were found to be coherent with the theoretical values. The flex resistance and the flexural rigidity of the samples with tungsten content were also investigated. The coated fabrics with different powder loadings and thicknesses showed good resistance against repetitive folding; on the other hand, the results showed that the increment of tungsten amount in the coating resulted in stiffer fabrics.

Core-sheath nanofibers are being developed with coaxial electrospinning for use in drug release studies. In this study, nanofiber structures were developed as hydrophobic PCL in the sheath and hydrophilic PVP in the core. The effect of polymer concentrations on fiber structure and water contact angle was observed by forming two different test groups. In the first group, fiber diameters were observed to decrease depending on viscosity as the polymer concentration decreased from 10% PCL / 10% PVP to 6% PCL / 6% PVP. It was also observed that the contact angle decreased from 104.3° to 57.61° as the concentration decreased. In the second group, the shell polymer ratio was kept constant as 10% wt PCL, while the core polymer ratio was decreased to 10 %, 8% and 6%. It was observed that the core polymer in the structure became hydrophilic as its viscosity decreased. Compared to the first group, the decrease in the contact angles of the surfaces was less since the shell polymer ratio was kept constant. Contact angles decreased from 104.3° to 96.29°.