Salinity is the major constraint that decreases the yield and production of crops. Wheat has a significant value in agricultural food commodities. The germination and growth of wheat seedlings are a big challenge in salt-affected soils. The seed priming technique is used to mitigate salt stress and enhance the germination and growth of the crops. Therefore, the current study was conducted to evaluate the hydropriming of natural plant extract (moringa leaf extract) and water on wheat seeds and grown under different saline (0, 0.05, 0.1, 0.15, and 0.2 M NaCl) environments. The germination attributes (germination percentage, germination index, mean germination day, coefficient of variance, vigor index) and seedling growth (fresh weight, dry weight, root length, shoot length) were enhanced in the plants primed by moringa leaf extract. The germination percentage was observed 10% more at 0.2 M NaCl stress in seeds treated with moringa leaf extract than seeds treated with water. The nutrient (K, Ca, Mg, P, S, Fe, B, Mn, Zn, Cu) uptake was also observed more in the shoots and roots of wheat seedlings soaked in moringa leaf extract as compared to soaked in water. Controlled plants showed higher concentrations of toxic ions (Na) and reactive oxygen species (H2O2) in shoots and roots of wheat seedlings. The use of moringa leaf extract for priming wheat seeds will enhance their germination and growth by maintaining efficient nutrient uptake and restricting the toxic ions and reactive oxygen species accumulation.
A method for the measurement of total mercury (T-Hg) in environmental samples using cold vapour atomic absorption spectrometry (CV AAS) has been validated yielding a dynamic range (0.04–10.00 μg/kg) and high certified reference material (CRM) recovery (>90%). The validation was carried out according to International Union of Pure and Applied Chemistry (IUPAC) validation and Eurachem Guides. A freeze-dried and homogenised sample was weighed and then digested using Suprapur acids (HNO3, H2SO4, and HF) with potassium dichromate solution in a hot block digestion system. A calibration curve was constructed (R2 > 0.999). Two CRMs (Marine Sediment Reference Material (PACS-3) and Trace Elements in Muscle Tissue (Trace Elements and Methylmercury in Mussel Tissue (NIST2976)) were utilised for quality assurance and control. The limit of quantification (LOQ) calculated as 0.04 µg/kg, and uncertainty (U) calculated as 2%. The obtained results showed the suitability of this method for direct mercury measurement in environmental samples. Additionally, the proficiency of this method was recognised by accreditation under the standard of International Organization for Standardization (ISO/IEC 17025:2017) for competence of testing and calibration laboratories.
The current study aimed to gauge total mercury (THg) concentration and the environmental geochemical indices in tarmat contaminated sediments and test their presence in targeted coastal species. Layers of hard asphalt-like tarmats and sediment samples were collected from 34 sites along the coast of Qatar. The mean concentration of THg in tarmat-sediment mixture is 89 ± 20 ng·g-1. THg concentration varies significantly between the northern and eastern coasts. Geographically, sampling area were divided into four zones according to the relative closeness with low to serious potential ecological risk index (Er), moderate pollution load index (PLI), moderate Geoaccumulation index (Igeo), and no toxic risk (TRI) trending as Northern (Zones 4, 3) > North-Eastern (Zone 1) > Western (Zone 2) coasts. Three biota classes (Gastropoda, Bivalvia, and Crustacea) were sampled on the tarmat which the hermit crab (Clibanarius signatus) from Ras Rakan island obtained the highest THg (977 ng·g-1) and BSAF (29.70).
In this study, the phytotoxic effects caused by the exposure to five different concentrations of two veterinary antibiotics (Tylosin, and Enrofloxacin) that are commonly used for the treatment of farm animals as antibacterial agents were considered. The impact of antibiotic residues was evaluated on the germination percentage, accumulation, and seedling elongation of the barley seeds using Petri dishes under controlled environmental conditions. The treatments were distributed randomly using Completely Randomized Design (CRD). The germination percentage was significantly inhibited with the increasing Enrofloxacin dose concentrations, while, it was to some extent on the contrary in the case of Tylosin, where seed germination was enhanced as a result of increasing Tylosin concentrations. Liquid chromatography-tandem mass spectrometry LC/MS-MS was used to detect and quantify the uptake dosage after drying and extracting the antibiotic compounds from the seedling.
Globally, urbanization, industrialization, and transportation have worsened urban air quality in recent decades. Using sustainable, cost-effective methods to monitor and reduce air pollution is crucial. The best Nature-based Solution (NbS) for urban environmental cleanup is plants. Roadside plants are key carriers of air pollution and have various tolerances. Ziziphus spina-christi’s air pollution tolerance was assessed using the Air Pollution Tolerance Index (APTI). The Bioconcentration Factor (BCF) examined the heavy metal accumulation capacity of Ziziphus spina-Christi’s fruits and leaves. Two sampling sites were studied: a reference location remote from human activity and a densely populated metropolitan region. Ziziphus spina-christi is considered a tolerant species in Qatar, based on its calculated value of APTI in this study. Both total chlorophyll and ascorbic acid influence APTI levels and have a strong positive correlation with APTI. BCF values in leaves were higher than fruits indicating that the leaves of Ziziphus spina-christi have a greater potential for metal absorption than its fruits. Moreover, the leaves of Ziziphus spina-christi showed a potential for mercury accumulation (BCF > 1), thus it is a good candidate to be used for phytoremediation in areas of mercury contamination. The integration of both APTI and BCF methods is significant and beneficial in advising policymakers and urban planners regarding suitable tree species for sustainable urban development.