The structural and gas-sensitive properties of n-N SnO2/κ(ε)-Ga2O3:Sn heterostructures were investigated in detail for the first time. The κ(ε)-Ga2O3:Sn and SnO2 films were grown by the halide vapor phase epitaxy and the high-frequency magnetron sputtering, respectively. The gas sensor response and speed of operation of the structures under H2 exposure exceeded the corresponding values of single κ(ε)-Ga2O3:Sn and SnO2 films within the temperature range of 25–175 °C. Meanwhile, the investigated heterostructures demonstrated a low response to CO, NH3, and CH4 gases and a high response to NO2, even at low concentrations of 100 ppm. The current responses of the SnO2/κ(ε)-Ga2O3:Sn structure to 104 ppm of H2 and 100 ppm of NO2 were 30–47 arb. un. and 3.7 arb. un., correspondingly, at a temperature of 125 °C. The increase in the sensitivity of heterostructures at low temperatures is explained by a rise of the electron concentration and a change of a microrelief of the SnO2 film surface when depositing on κ(ε)-Ga2O3:Sn. The SnO2/κ(ε)-Ga2O3:Sn heterostructures, having high gas sensitivity over a wide operating temperature range, can find application in various fields.
Pt/(100) β-Ga2O3 Schottky barrier diodes were fabricated using a plate cleaved from the crystal grown by Czochralski method. Their electroconductive and photoelectric characteristics were studied. The following values were obtained: the Schottky barrier height (1.69/1.62/1.74 eV), ideality coefficient (1.09/1.14), saturation current density (9.91 × 10–15 A/cm2), diode series resistance (7.98 kΩ), and net donor concentration [(1.8–2.4) × 1018 cm–3]. The diodes demonstrate a high rectification ratio of 1010 at an applied voltage of ± 1 V and a relatively low experimental value of the leakage current density ∼10–11 A/cm2. These structures are solar-blind and also capable of operating in self-powered mode. The diodes are highly sensitive to short-wave ultraviolet radiation with a wavelength λ ≤ 265 nm. The maximum values of responsivity (20.4 A/W), external quantum efficiency (1.2 × 104%), and detectivity (9.6 × 1015 Hz0.5 × cm × W–1) of diodes were registered under exposure to irradiation at λ = 210 nm and at applied voltage of −1 V. The responsivity and external quantum efficiency values in the self-powered operation mode were 12.3 A/W and 7.2 × 103%, respectively. The diodes showed low rise and decay times in self-powered operation mode for photodiode based on Ga2O3: 14 and 30 ms, respectively.
The effect of mechanical tension on the multifractal characteristics of the lateral surface of a Fe77Ni1Si9B13 amorphous alloy is studied by scanning tunneling microscopy (STM). It is established that, at small loads, the surface is smoothed out much as a crumpled sheet of paper is smoothed out under tension. With an increase in the load, there appears a tendency to the formation of a fractal structure on the surface.
The influence of isothermal annealing on the chemical composition, microstructure, and surface relief of ribbons of an amorphous Fe77NiSi9B13 alloy was studied using Auger electron spectroscopy and transmission electron, atomic-force, and scanning tunneling microscopy. It is established that an annealing below the glass transition temperature results in a boron enrichment of the ribbon surface layer on the side of the ribbon that was not in contact with the roller during quenching. On both sides of a ribbon, islands of crystallized material 2–5 μm in size appear consisting of nano-and microcrystals of α-Fe on the roller-contacting side and of iron boride on the opposite side. The surface relief on the roller-contacting side of a ribbon and that on the opposite side are shown to differ in terms of their spectral and fractal characteristics after annealing. The effect of the chemical composition and excess free volume of the surface layer on the formation of islands of crystallized material and surface relief is discussed.