For the first time, Hispano‐Moresque glazed tiles from Portuguese and Spanish collections were studied together and compared. This work is included in a wider study tackling the technology of Hispano‐Moresque tile production from several collections in the Iberian Peninsula. While showing many similarities, differences were identified between collections, regarding both chemical and morphological characteristics. The collection from the Mosteiro de Santa Clara‐a‐Velha (Coimbra) stands out from the other collections, with higher SnO₂ content (up to 14 wt%), the highest Fe₂O₃ contents in amber glazes and a Ca‐rich interface layer (mostly comprised of wollastonite, CaSiO₃). Samples from Palácio Nacional de Sintra (near Lisbon) and Seville‐attributed samples (from the Instituto Valencia de Don Juan) are chemically similar, except that most Sintra's samples display a K‐rich glaze/ceramic interface, whereas the ones from Seville exhibit both K‐rich and Ca‐rich inclusions. The samples attributed to Toledo show glazes with many inclusions, contrasting with the homogeneous glazes in most Hispano‐Moresque tiles. From these results, we identify differences that can be used as markers in future studies on Hispano‐Moresque tiles.

This work explores the combination of µ-Raman spectroscopy and scanning electron microscopy with X-ray energy dispersive spectrometry (SEM-EDS) for the study of the glazes in 15th–16th century Hispano-Moresque architectural tiles. These are high lead glazes that can be tin-opacified or transparent, and present five colors: tin-white, cobalt-blue, copper-green, iron-amber, and manganese-brown. They are generally homogenous and mineral inclusions are mostly concentrated in the glaze-ceramic interface. Through SEM-EDS, these inclusions were observed and chemically analyzed, whereas µ-Raman allowed their identification on a molecular level. K-feldspars, wollastonite and diopside were the most common compounds, as well as cassiterite agglomerates that render the glaze opaque. Malayaite was identified in green glazes, and andradite and magnesioferrite in amber glazes. Co–Ni–ferrites were identified in blue glazes, as well as Ni–Fe–olivines. Manganese-brown is the color where most compounds were identified: bustamite, jacobsite, hausmannite, braunite, and kentrolite. Through the µ-Raman analysis of different areas in large inclusions previously observed by SEM, it was possible to identify intermediate phases that illustrate the reaction process that occurs between the color-conferring compounds and the surrounding lead glaze. Furthermore, the obtained results allowed inference of the raw materials and firing temperatures used on the manufacture of these tiles.

During an archaeological intervention that took place in Beja (southern Portugal), at Avenida Miguel Fernandes, between August 2003 and March 2004, a set of 137 silos was discovered. The excavation yielded an assemblage of glass that can be dated between the fourteenth and the seventeenth centuries. For this investigation only the fragments from the medieval contexts were considered in order to provide an overview of the use of glass vessels in a Portuguese town in the fourteenth and fifteenth centuries. A group of eleven medieval glass fragments was chemically characterised by means of µ-PIXE (particle-induced X-ray emission) and UV-vis reflectance spectroscopy. Analysis by µ-PIXE enabled the determination of the chemical composition, and UV-vis reflectance spectroscopy was used as a complementary technique to identify the metallic elements responsible for different colours observed in the glasses. Results showed that the analysed objects are in the majority made of a soda-lime silica glass, indicating a connection with the Mediterranean tradition. Cobalt and copper were the colorants used to obtain the blue and turquoise glasses, respectively, whereas iron is responsible for the green and yellow colours.