The inter-critically reheated grain coarsened heat affected zone (IC GC HAZ) has been reported as one of the most brittle section of high-strength low-alloy (HSLA) steels welds. The presence of micro-alloying elements in HSLA steels induces the formation of microstructural constituents, capable to improve the mechanical performance of welded joints. Following double welding thermal cycle, with second peak temperature in the range between Ac1 and Ac3, the IC GC HAZ undergoes a strong loss of toughness and fatigue resistance, mainly caused by the formation of residual austenite (RA). The present study aims to investigate the behavior of IC GC HAZ of a S355 steel grade, with the addition of different vanadium contents. The influence of vanadium micro-alloying on the microstructural variation, RA fraction formation and precipitation state of samples subjected to thermal cycles experienced during double-pass welding was reported. Double-pass welding thermal cycles were reproduced by heat treatment using a dilatometer at five different maximum temperatures of the secondary peak in the inter-critical area, from 720 °C to 790 °C. Although after the heat treatment it appears that the addition of V favors the formation of residual austenite, the amount of residual austenite formed is not significant for inducing detrimental effects (from the EBSD analysis the values are always less than 0.6%). Moreover, the precipitation state for the variant with 0.1 wt.% of V (high content) showed the presence of vanadium rich precipitates with size smaller than 60 nm of which, more than 50% are smaller than 15 nm.

Structural applications that use High-Strength Low-Alloy (HSLA) steels require detailed microstructural analysis to manufacture welded components that combine strength and weldability. The balance of these properties depends on both the chemical composition and the welding parameters. Moreover, in multi-pass welds, thermal cycling results in a complex Heat-Affected Zone (HAZ), characterized by sub-regions with a multitude of microstructural constituents, including brittle phases. This study investigates the influence of Vanadium addition on the microstructure and performance of the HAZ. Multi-pass welded joints were manufactured on 15 mm thick S355 steels with different Vanadium contents using a robotic GMAW process. A steel variant containing both Vanadium and Niobium was also considered, and the results were compared to those of standard S355 steel. Moving through the different sub-regions of the welded joints, the results show a heterogeneous microstructure characterized by ferrite, bainite and martensite/austenite (M/A) islands. The presence of Vanadium reduces carbon solubility during the phase transformations involved in the welding process. This results in the formation of very fine (average size 11 ± 4 nm) and dispersed precipitates, as well as a lower percentage of the brittle M/A phase, in the variant with a high Vanadium content (0.1 wt.%), compared to the standard S355 steel. Despite the presence of the brittle phase, the micro-alloyed variants exhibit strengthening without loss of ductility. The combined presence of both hard and soft phases in the HAZ provides stress-damping behavior, which, together with the very fine precipitates, promises improved resistance to crack propagation under different loading conditions.