To realize fast synthesis of cadmium sulfide (CdS) quantum dots with a low-toxic material, a one-step synthesis method is investigated and conducted. Potato extract is used as a stabilizer and modifier, by which aqueous CdS quantum dots can be prepared at a lower temperature with a shorter time. Through systematic characterization and analysis, a green and fast synthesis mechanism is demonstrated in detail. And the nanoscale CdS quantum dots are uniform in size and dispersity. With low cost and high sensitivity, the prepared CdS quantum dots show promising application in silver-ion detection. This method shows great significance for an environmentally friendly and facile synthesis of CdS quantum dots.

In this study, a novel method was adopted to construct a CdS–TiO₂ heterostructure to degrade penicillin under sunlight. A potato extract was used during the synthesis process of CdS QDs as a stabilizer and a modifier. The CdS–TiO₂ composite with a heterostructure delivers high photocatalytic degradation efficiency. In detail, 0.6 mg/mL of CdS–TiO₂ can successfully decompose penicillin after 2 h, and 5‰ CdS–TiO₂ shows the optimal degradation efficiency with the degradation rate reaching 88%. Furthermore, the underlying mechanisms of the penicillin decomposition reaction were investigated by the EPR test and trapping experiment. It was found that the high photocatalytic degradation efficiency was attributed to the heterojunction of CdS–TiO₂, which successfully suppresses the recombination of the conduction band of CdS and the valence band of TiO₂. Moreover, it was confirmed that the reaction is the O₂-consuming process, and introducing O₂ can greatly accelerate the generation of a superoxide radical during the photocatalytic degradation process, which eventually improves the degradation of penicillin and shortens the degradation time. Finally, this work provides the possible penicillin degradation pathways, which will inspire the researchers to explore and design novel photocatalysts in the field of wastewater treatment in the future.