Mica is a harmful substance in sand and occurs frequently. The application of super standard mica sand is a difficult problem in large-scale engineering. In this work, the effects of an interface modifier, mineral admixture, and a curing system on the properties of cement-based materials with super standard mica sand were studied. The strength of cement-based materials linearly decreases with the mica content in sand. When the mica content in sand exceeds 6%, the compressive strength of mortar and concrete at 28 d decreases by more than 22.3% and 33.5%, respectively. By adding the silane coupling agent (SCA) of 50% mica mass and curing in natural conditions, the compressive strength of mortar increases by 10.9%. The cement-based materials with the SCA are more suitable for curing in natural conditions, and the performance of the SCA will not be affected by adding appropriate amounts of mineral admixture. The drying shrinkage strain of the concrete, with the sand containing high mica content modified by SCA, is reduced by 10.5%, and the diffusion of chloride ions in concrete is reduced. The XRD results show that the addition of the interfacial agent does not change the hydration products. The MIP and SEM results show that the SCA can form a bridge structure between the hydration products and the mica, improve the bonding strength of the interface zone, and reduce the number of harmful pores.

Fly ash (FA) and limestone powder (LS) are both environmentally friendly substitutes for cement. The mechanical strength and durability of hydraulic concrete with FA and LS cured under low temperature deserve attention. In this study, the mechanical strength and durability properties of cement mortar based on FA and LS cured under a low temperature of 5 °C were investigated. The compressive strength and resistance to freeze–thaw cycles and chloride ions of mortar with FA and LS were evaluated. The results reveal that adding 5% LS can increase the compressive strength of mortar containing 30% FA by 14.31% at 3 d and 1.63% at 180 d. The addition of 5% LS can result in a 0.58% reduction in the mass loss rate and an increase of 2.98% in RDM compared to the mortar with 30% FA after 100 freeze–thaw cycles. Meanwhile, the addition of 5% LS results in a 5.68% reduction in the chloride diffusion coefficient compared to the mortar with 30% FA. However, for the mortar containing 60% FA, any proportion of LS cannot increase the compressive strength of FA mortar from 3 d to 180 d and will decrease the resistance to freeze–thaw cycles and chloride ions. For the mortar containing 30% FA, the addition of 5% LS can promote the hydration product of C-S-H and obtain the minimum total amount of large capillary pores and air pores. Adding 10% LS can result in the mortar with 30% FA obtaining the lowest unit CO₂ emission, and adding 5% LS can result in the mortar with 60% FA obtaining the lowest unit CO₂ emission.