In this work a purification route of precursors for ionic liquids tailored to electrochemical energy storage systems is reported and described. The study was carried out on the N-butyl-N-methylpyrrolidinium bromide (PYR₁₄Br) precursor, which represents the intermediate product of the synthesis process of the N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR₁₄TFSI) hydrophobic ionic liquid. The target is to develop an easy and cost-effective approach for efficiently purifying several kinds of ionic liquid precursors and determining their purity content. The PYR₁₄Br precursor was synthesized through an eco-friendly preparation procedure, which requires water as the only processing solvent, and purified through sorbent materials, such as activated charcoal and alumina. The effect of the treatment/nature/content of sorbents and processing temperature/time was investigated. The impurity content was detected by UV-VIS spectrophotometry measurements. Additionally, a correlation between the measured absorbance and the content of impurities within the precursor was obtained. The purity level of the precursor was seen to play a key role in the electrochemical performance of the ionic liquids.

Thermal energy storage (TES) systems are crucial for industries to overcome the temporal misalignment between heat demand and availability, while also reducing greenhouse gas emissions. This is fundamental for increasing industrial production efficiency and promoting renewable energy sources, such as solar energy. Among various TES solutions (sensible, latent, and thermochemical), combined sensible/latent heat TES (CSLHTES) is attracting more interest. It combines the ideal characteristics of individual sensible or latent heat storage technologies: high stored energy density, compactness, high efficiency, stable heat supply temperature, and good power output. This work experimentally evaluates the thermal behavior and potential improvements of a CSLHTES system. This system, named HyTES, consists of two series-connected TES units—one sensible and one latent—operating within a 180–280 °C range, to meet typical industrial application requirements. A test procedure was developed to define key performance indexes (KPIs). The results confirm that CSLHTES systems generally show improved performance compared to individual units. This indicates that further analysis of this approach is justified, moving beyond just energy and exergy perspectives to also include economic and environmental impacts.

Concentrated Solar Power (CSP) plants integrated with Thermal Energy Storage (TES) represent a promising renewable energy source for generating heat and power. Binary molten salt mixtures, commonly referred to as Solar Salts, are utilized as effective heat transfer fluids and storage media due to their thermal stability and favorable thermophysical properties. However, these mixtures pose significant challenges due to their high solidification temperatures, around 240 °C, which can compromise the longevity and reliability of critical system components such as pressure sensors and bellows seal globe valves. Thus, it is essential to characterize their performance, assess their reliability under various conditions, and understand their failure mechanisms, particularly in relation to temperature fluctuations affecting the fluid’s viscosity. This article discusses experimental tests conducted on a pressure sensor and a bellows seal globe valve, both designed for direct contact with molten salts in CSP environments, at the ENEA Casaccia Research Center laboratory in Rome. The methodology for conducting these experimental tests is detailed, and guidelines are outlined to optimize plant operation. The findings provide essential insights for improving component design and maintenance to minimize unplanned plant downtime. They also offer methodologies for installing measurement instruments and electrical heating systems on the components.

Concentrated Solar Power (CSP) plants integrated with Thermal Energy Storage (TES) represent a promising renewable energy source for generating heat and power. Binary molten salt mixtures, commonly referred to as Solar Salts, are utilized as effective heat transfer fluids and storage media due to their thermal stability and favorable thermophysical properties. However, these mixtures pose significant challenges due to their high solidification temperatures, around 240 °C, which can compromise the longevity and reliability of critical system components such as pressure sensors and bellows seal globe valves. Thus, it is essential to characterize their performance, assess their reliability under various conditions, and understand their failure mechanisms, particularly in relation to temperature fluctuations affecting the fluid’s viscosity. This article discusses experimental tests conducted on a pressure sensor and a bellows seal globe valve, both designed for direct contact with molten salts in CSP environments, at the ENEA Casaccia Research Center laboratory in Rome. The methodology for conducting these experimental tests is detailed, and guidelines are outlined to optimize plant operation. The findings provide essential insights for improving component design and maintenance to minimize unplanned plant downtime. They also offer methodologies for installing measurement instruments and electrical heating systems on the components.

Parabolic trough collector (PTC) plants that use solar salt as a heat transfer fluid face operational challenges due to the salt’s relatively high solidification temperature of around 240 °C, which can compromise reliability if solidification occurs within receiver tubes or piping. While electric tracing cables are typically used to heat piping, they cannot be installed on PTC receivers due to the presence of external glass covers. As an alternative, impedance heating can be employed, applying voltage directly to the steel receivers, which act as resistive heaters. This study presents experimental results on the phase-change behavior of solar salt within receivers, focusing on melting and solidification times. Tests were conducted using two dedicated receivers under vacuum and non-vacuum conditions. Under vacuum, complete melting was achieved at 4.5 V and 1.43 kW in 5.5 h, while solidification from 270 °C took about 4 h, progressing inward from the tube connections. For non-evacuated receivers, 7 V and 3.2 kW were needed for melting in 5.6 h, and solidification at 270 °C was completed in 1.45 h. These outcomes illustrate that non-evacuated tubes require nearly twice the power and have a 2.8-fold increase in heat loss rate, offering quantitative guidance for vacuum loss detection in PTC systems.