Biochar is a solid material formed during biomass thermochemical decomposition processes. This organic compound has particular properties that may cause effects on soils depending on its feedstock and processing conditions. Thus, the characteristics and purpose of use of this material must be recognized prior to its use. Two types of biochar, derived from different wood sources, were compared, one from caatinga biome species and another from cashew trees. Two species from caatinga biome were used, jurema-preta (Mimosa tenuiflora Willd. Poir.), and marmeleiro (Croton sonderianus Müll. Arg.). This study aimed to identify the best biochar material regionally available to increase water-holding capacity in the soil, based on laboratory tests and microstructural porosity evaluation. Biochar from Caatinga wood demonstrated an improved water-holding capacity if compared to cashew wood biochar. The particle diameters of 2 and 4 mm showed the highest levels, which were 2,268 g.g^-1 for caatinga wood and 0.574 g.g^-1 for cashew wood biochars, respectively. While the smaller quantities of macropores and a larger number of micropores (smaller radius) could explain the higher water-holding capacity for biochar from caatinga wood, the thick lignified cell walls of biochar from cashew wood support the idea of a hydrophobic effect contributing to water lower holding capacity.