Automatic proportional integral derivative control techniques are applied in a single-stage solar absorption cooling system, showing 3.8 kW (~1 ton) cooling capacity, with a coefficient of performance of 0.6 and −4.1 °C evaporator cooling temperature. It is built with plate heat exchangers as main components, using ammonia–water as the working mixture fluid and solar collectors as the main source of hot water. Control tuning was verified with a dynamical simulation model for a solution regarding mass flow stability and temperature control in the solar absorption cooling system. The controller improved steady thermodynamic state and time response. According to experimental cooling temperatures, the system could work in ranges of refrigeration or air-conditioning end-uses, whose operation makes this control technique an attractive option to be implemented in the solar absorption cooling system.

This study presents the experimental and thermodynamic evaluation of a solar thermochemical refrigeration system (STRS) powered by evacuated tube solar collectors with heat pipes as thermal energy sources, using industrial-grade BaCl₂–NH₃. The system was designed to produce refrigeration and ice using industrial-grade BaCl₂–NH₃ without additional additives or electrical input. Experimental tests were conducted under real-world conditions, with generation temperatures between 55 and 66 °C and solar irradiance of 750 to 900 W/m². The system achieved efficient ammonia desorption, yielding up to 4.2 L of refrigerant and demonstrating repeatable operation over several thermochemical cycles. During the nighttime absorption–evaporation process, the STRS reached evaporation temperatures of −7 to −3 °C and absorption temperatures between 24 and 31 °C, suitable for ice production. The internal coefficient of performance ranged from 0.244 to 0.307, with an overall efficiency of 0.146 to 0.206. The experimental data obtained were used to derive pressure–temperature equilibrium equations for the BaCl₂–NH₃ working pair, yielding correlation coefficients greater than 0.98, which confirms thermodynamic consistency. The results demonstrate that additive-free, industrial-grade BaCl₂ can achieve high efficiency at low temperatures, making this system a cost-effective and sustainable alternative for refrigeration and cold storage in rural areas. This research contributes new experimental knowledge on low-temperature thermochemical refrigeration and supports future development toward quasi-continuous optimization cycles based on experimental data.