AI is reshaping how organizations approach environmental, social, and governance (ESG) performance, yet the scholarly literature examining this intersection remains fragmented. This study presents a bibliometric and knowledge mapping review of 1,959 publications from the Web of Science Core Collection and Scopus databases (2010-2026). Using a multidimensional methodological approach that combines performance analysis, co-word analysis, co-citation analysis, bibliographic coupling, co-authorship analysis, thematic evolution, thematic mapping, burst detection, and citation path analysis. We apply sophisticated Python-based analytics for bibliometric analysis and map the conceptual, intellectual, and social structures of this emerging field. Our findings reveal explosive growth beginning in 2020, with China, the United States, and the United Kingdom as the most prolific contributors. The conceptual landscape centers on seven distinct themes, anchored by artificial intelligence, ESG, machine learning, sustainability, and green innovation. Thematic evolution traces a clear progression from foundational discussions (2010-2015) toward applied AI-driven ESG applications (2021-2026). Emerging frontiers, including generative AI for ESG reporting, explainable AI in sustainability governance, and AI-enabled greenwashing detection, signal where the field is heading. We contribute an integrated theoretical framework bridging traditional strategic management theories with AI-specific perspectives, including algorithmic opacity and socio-technical systems theory. These findings offer a foundation for future scholarship and practical guidance for managers and policymakers navigating the intersection of AI and sustainability.