This paper summarizes the research progress and applications of oxygen-reduced-air-assisted gravity drainage (OAGD) in enhanced oil recovery (EOR). The fundamental principles and key technologies of OAGD are introduced, along with a review of domestic and international field trials. Factors influencing displacement performance, including low-temperature oxidation reactions, injection rates, and reservoir dip angles, are discussed in detail. The findings reveal that low-temperature oxidation significantly improves the recovery efficiency through the dynamic balance of light hydrocarbon volatilization and fuel deposition, coupled with the synergistic optimization of the reservoir temperature, pressure, and oxygen concentration. Proper control of the injection rate stabilizes the oil–gas interface, expands the swept volume, and delays gas channeling. High-dip reservoirs, benefiting from enhanced gravity segregation, demonstrate superior displacement efficiency. Finally, the paper highlights future directions, including the optimization of injection parameters, deepening studies on reservoir chemical reaction mechanisms, and integrating intelligent gas injection technologies to enhance the effectiveness and economic viability of OAGD in complex reservoirs.
Organic chlorine (Org-Cl) in crude oil poses continuous operational and environmental risks during production, trading, and refining processes. This article reviews the management of Org-Cl from its origin assumptions to analysis and mitigation measures and proposes a practical closed-loop framework. Quantitative merit value indicators (typical detection limit/quantitative limit, accuracy, and repeatability) and greenness indicators are used to compare standard methods and advanced methods, and to guide the selection of applicable methods. Corresponding technical maturity levels (TRLs) are assigned to mitigation measures (protective beds/adsorption, HDC, and emerging electrochemical/photochemical routes). Technical economic indicators with reference values (relative capital expenditure/operating expenditure levels) are summarized to assist decision-making. The main findings are as follows: (i) Evidence of secondary formation of organic chlorine under distillation-related conditions still relies on the matrix and requires independent verification; (ii) MWDXRF can achieve rapid screening (usually only 5 to 10 min), while CIC/D5808 supports quality balance arbitration; (iii) adsorption can remove a considerable portion of organic chlorine in light fractions under laboratory conditions, while the survival ability of HDC related to crude oil depends on the durability of the catalyst and the tail gas treatment capacity; and (iv) minimum viable implementation (MVI) combined with online total-chlorine monitoring and a physical principle-based digital twin technology can provide auditable closed-loop control. The limitations of this review include partial reliance on laboratory-scale data, inconsistent reports among studies, and the lack of standardized public datasets for model benchmarking. Prioritization should be given to analysis quality control, process durability indicators, and data governance to achieve reliable digital deployment.
As the development of oilfields in China enters its middle-to-late stage, the old oilfields still occupy a dominant position in the production structure. The seepage process of reservoirs in the high Water Content Period (WCP) presents significant nonlinear and non-homogeneous evolution characteristics, and the traditional seepage-modeling methods are facing the double challenges of accuracy and adaptability when dealing with complex dynamic scenarios. In recent years, Deep Learning technology has gradually become an important tool for reservoir seepage field prediction by virtue of its powerful feature extraction and nonlinear modeling capabilities. This paper systematically reviews the development history of seepage field prediction methods and focuses on the typical models and application paths of Deep Learning in this field, including FeedForward Neural networks, Convolutional Neural Networks, temporal networks, Graphical Neural Networks, and Physical Information Neural Networks (PINNs). Key processes based on Deep Learning, such as feature engineering, network structure design, and physical constraint integration mechanisms, are further explored. Based on the summary of the existing results, this paper proposes future development directions including real-time prediction and closed-loop optimization, multi-source data fusion, physical consistency modeling and interpretability enhancement, model migration, and online updating capability. The research aims to provide theoretical support and technical reference for the intelligent development of old oilfields, the construction of digital twin reservoirs, and the prediction of seepage behavior in complex reservoirs.
In the context of the “dual-carbon” strategy and the escalating challenges posed by ultra-high water-cut reservoirs, the development of green and intelligent profile control gels (PCGs) has become essential for balancing enhanced oil recovery (EOR) efficiency with environmental sustainability. In this study, a green performance evaluation framework integrating the Environmental Toxicity Index (ETI) and Carbon Footprint Intensity (CFI) is established to quantitatively assess the environmental friendliness of polymer gel systems. Representative gel types—including conventional chromium(III)–polyacrylamide(Cr(III)–PAM), citric acid–chitosan, and pH-responsive nanogels—are evaluated to reveal their structure–environment interactions. Comparative analysis shows that the Cr(III)–PAM system exhibits strong plugging capability but imposes the highest environmental burden (ETI = 1.45; CFI = 9.1 kg CO2e/kg), whereas the citric acid–chitosan system significantly reduces both toxicity (ETI = 0.42) and carbon footprint (CFI = 2.1). Meanwhile, pH-responsive nanogels demonstrate superior reservoir stability and sustainability under harsh conditions. The proposed ETI–CFI evaluation framework not only enables quantitative benchmarking of green performance but also provides a unified criterion for molecular design, material screening, and engineering application of intelligent green gels. This framework offers practical guidance for the low-carbon transformation of oilfield chemical systems, aligning innovation with sustainability objectives and supporting the realization of dual-carbon goals.