Polychlorinated biphenyls (PCBs) have been withdrawn from the market due to their toxicity, bioaccumulation capacity, and persistence. PCBs have been observed to potentially form in combustion processes under appropriate conditions and in the presence of precursors containing chlorine. The study covered a municipal waste incineration plant and an industrial waste incineration plant. The objective of the study was to assess the effect of these objects on PCB accumulation in soil and plants taking into account the distance from the emission object and wind direction. Soil samples were collected from layers: 0-5, 5-10, 10-20, and 20-30 cm. Test plants were collected from the same areas as the soil samples. The highest accumulation of PCBs was found in plants with large leaf area. Around the municipal waste incineration plant, these wereTanacetum vulgareleaves (12.45 ng/g), and around the industrial waste incineration plant–grasses (4.3 ng/g). In the case of soils, the accumulation of PCBs for both kind waste incinerators was similar, reaching approximately 3 ng/g. As the distance from the municipal waste incinerator and industrial waste incinerator increased, the accumulation of PCBs in the soil decreased. For municipal waste incinerator, no effect of wind direction on PCB accumulation in the soil was observed. In the majority of cases, the accumulation of PCBs in soils taken from the leeward side of the industrial waste incinerator was higher than that in soils from the windward side. In soils around the municipal waste incinerator, PCB compounds moved deep into the soil and reached the highest accumulation in the soil layer of 10-20 cm or 20-30 cm. In soils around the industrial waste incinerator, the highest accumulation of PCBs occurred in the soil layer of 0-5 cm.
This study aimed to investigate the impact of municipal waste landfill on polychlorinated biphenyls (PCBs) release to the environment concerning groundwater flow directions. The contents of polychlorinated biphenyls in soils, plants and water were analysed at various distances from the landfill. Thanks to low solubility PCBs in water groundwater flow direction, under the landfill, have an influence on PCBs concentration in groundwater. Strong PCBs’ sorption to organic matter caused that no affect groundwater flow directions on PCB content in soils and plants’ tissues was observed. The largest PCBs deposition zone was located 50 m from the contamination source (landfill). Tri-CB and tetra-CB homologues were capable of migration deep into the soil profile, which could be related to the geological material from which the soils under study were developed, as well as to the properties of the PCB homologues.
In this chapter, the life cycle assessment was presented as a tool to implement sustainable development in the bioeconomy and circular economy. Bulky waste includes large items such as furniture, doors, flooring and mattresses. The management of bulky waste is a serious problem for European countries. The URBANREC project proposed a solution to this problem through the use of new technologies for the bulky waste processing. The aim of the URBANREC project is to implement an eco-innovative, integrated system of bulky waste management and demonstrate its effectiveness in various regions of Europe. The project has received funding from the European Union. In this chapter, the LCA environmental analysis was performed for the technology of grinding bulky waste using a water jet by the Ecofrag company. The calculations were carried out using SimaPro 8.5.2.0. The LCA analysis shows that the reuse of foams and mattresses contributes to the avoidance of their targeted production, which is related with the reduction of greenhouse gas emission and consumption of fossil raw materials.
Butanol is currently produced on an industrial scale, primarily from fossil-based raw materials. An alternative method involves gas fermentation. To improve the efficiency of microbial processes, one promising approach is electrofermentation, which involves the application of an electric current to stimulate microbial growth or modulate metabolic pathways. This study examined the production of biobutanol from gas fermentation supported by electrofermentation, as assessed through a Life Cycle Assessment (LCA). The LCA was conducted for a biobutanol production technology developed within the framework of the BesTECH project, funded in the ERA-NET Bioenergy programme. Two environmental impact assessment methods were applied: ReCiPe 2016 and IPCC 2021 GWP 100 (with CO2 absorption considered). The results of the LCA indicated that the most significant environmental impact is associated with greenhouse gas emissions from fossil fuel combustion used to generate electricity (based on Austria’s energy mix). An additional environmental burden is related to the production of the fermentation medium. Sensitivity analysis revealed that the environmental performance of the process is strongly influenced by the source of electricity used in biobutanol production.