Recovery of nutrients from biomass combustion ash is of great importance for sustainable bioenergy waste use. In this work, granulated fertilizer materials were engineered from biofuel bottom ash, lime kiln dust and water, analysed for their chemical complexity and tested in pot experiments (2017–2018) for their propensity to release nutrients. The results obtained in this work showed that spring barley yield was observed to be the highest for granulated biomass ash with 30% of ash in the granule. The yield increased 3.99 t ha⁻¹ per 100 kg ha⁻¹ potassium oxide (K₂O) in 2017 and 1.23 t ha⁻¹ per 100 kg ha⁻¹ K₂O in 2018. Straw yield varied between 1.39–5.08 t ha⁻¹/100 kg ha⁻¹ in 2017 and 0.36–1.23 t ha⁻¹/100 kg ha⁻¹ in 2018. Calcium concentration significantly increased in soil. No significant changes in soil mobile phosphorus (P) were obtained as well as for the heavy metal concentrations in soil. This suggests that biofuel ash can be a significant source of certain major nutrients for crops that can also beneficially affect soil pH. The results of this work can provide policy-makers with the information needed to diversify existing and enable new biomass bottom ash utilization routes which currently vary significantly between the countries.

Studies on the mineral content of different rosehip species/cultivars during the ripening period are very limited. Therefore, the objective of this research was to evaluate the content and composition of the mineral elements of two species and two rosehip cultivars growing on an organic farm. The rosehip fruits were harvested at different ripening stages, five time per season. Mineral composition (K, Ca, Mg, P, Fe, Na, Ti, Cu, B, Mn, Al, Zn, Cr, Co, Ni, As, Mo, Cd and Pb) was analyzed by means inductively coupled plasma mass spectrometry (ICP–MS). The results showed that the ripening stage and species/cultivars had an effect on the contents of the mineral elements. Significantly, the highest content of mineral elements was determined at ripening stage I (Ca, Mg, Ti, Mn, Al and Cr) and IV (K, P, Fe, Cu and B). Species of the Rosa canina accumulated the highest content of mineral elements. Correlation analysis showed that the hue angle had a positive and very strong relationship with six mineral elements: K (r = 0.909), Ca (r = 0.962), Mg (r = 0.965), P (r = 0.945), Fe (r = 0.929) and Ti (r = 0.944).

This study evaluates the environmental impact assessment of sustainable pig farm via management of nutrient and co-product flows in the farm. Manure management and biogas production are among the most promising pathways towards fully utilizing organic waste within a circular bioeconomy as the most environmentally friendly solution mitigating gaseous emissions and producing bioenergy and high-quality bio-fertilizers. The concept of farm management includes rearing pig, growing all the feeds needed, and managing the nutrients and co-product flows in the farm. A consequential life cycle assessment (LCA) was performed to examine three scenarios in which all the generated manure is used as fertilizer for barley cultivation and mineral fertilizer is used where necessary (SC1); produced surplus straw is used for thermal energy generation and maize is used for sale, substituting maize biomass in the market (SC2); and all co-products are circulated in a closed system (SC3). The functional unit (FU) was defined as a “farm with 1000 fattening pigs at farm gate”. The analysis showed that heat generation from wheat, barley and legumes straw has a significantly higher positive environmental impact than the use of these cereal straw for biogas production. The partial replacement of mineral fertilizers with digestate has positive environmental effects in terms of abiotic depletion, photochemical oxidation, terrestrial ecotoxicity, freshwater aquatic ecotoxicity, human toxicity, and marine aquatic ecotoxic aspects. The amount of digestate generated on a farm is not sufficient to completely eliminate the use of mineral fertilizers for plant fertilization. The generated pig manure (SC1) and digestate (SC2) is only enough for the fertilization of 8.3% of the total cultivated land of farm applying 22.9 t/ha rate.

Extensive application of mineral fertilizers resulted in high soil acidity, which is one of the major problems for crop production and soil degradation. Industrial solid waste, such as lime kiln dust and wood ash, can be used as alternative liming materials to benefit sustainable agricultural development. In this work, pelletized lime kiln dust with and without wood ash was utilized as liming material and the results of the three-year field study were compared with conventional mineral-based liming materials. It was determined that pelletized lime kiln dust satisfies the requirements posed by the recent European Union regulations to qualify as liming materials. The application of 2000 kg/ha Ca equivalent pelletized lime kiln dust increased soil pH_KCl by ~0.55 pH units. Moreover, pelletized lime kiln dust significantly increased spring wheat grain yields ranging from 33.6% to 40.4%, depending on the pellet size. The usage of these liming materials not only increased crop yield but also decreased heavy metal concentration in soil. Due to high alkalinity, carbonate content, easy handling, and the transportation of pelletized lime kiln dust with and without wood ash, the materials have the potential to be used in agriculture as liming materials to reduce soil acidification and increase crop productivity or be used as soil amendments.

The use of major nutrient-containing solid residuals, such as recycled solid waste materials, has a strong potential in closing the broken nutrient cycles. In this work, biofuel ash (BA) combined with green waste compost (GWC) was used as a nutrient source to improve soil properties and enhance wheat and triticale yields. The main goal was to obtain the nutrient and heavy metal release dynamics and ascertain whether GWC together with BA can potentially be used for concurrent bioremediation to mitigate any negative solid waste effects on the environment. Both BA and GWC were applied in the first year of study. No fertilization was performed in the second year of the study. The results obtained in this work showed the highest spring wheat yield when the GWC (20 t ha⁻¹) and BA (4.5 t ha⁻¹) mixture was used. After the first harvest, the increase in the mobile forms of all measured nutrients was detected in the soil with complex composted materials (GWC + BA). The content of heavy metals (Cd, Zn, and Cr) in the soil increased significantly with BA and all GWC + BA mixtures. In both experiment years, the application of BA together with GWC resulted in fewer heavy metals transferred to the crops than with BA alone.