High-strength concrete (HSC) is widely used in coastal regions, but its durability and structural safety is threatened by chloride ingress in marine environments. This study investigates the effects of different curing methods, normal, steam, and high-temperature autoclave on the chloride resistance of HSC using the electric flux test. A critical chloride concentration of 4.5% was identified, and accelerated deterioration tests were conducted to evaluate mechanical properties development (compressive strength, elastic modulus, toughness, specific toughness) under the various curing conditions. Additionally, the development of hydration products and microstructural characteristics were analyzed to elucidate the mechanisms underlying the observed differences. The results indicate that steam and autoclave curing enhance cement hydration and the initial mechanical properties of HSC but also increase permeability and susceptibility to chloride ion penetration compared to normal curing. Chloride penetration was found to be most severe at moderate chloride concentrations (~4.5%), while higher concentrations resulted in reduced ion migration. Although intensive curing under elevated temperature and pressure improves early strength and stiffness, it accelerates mechanical degradation under chloride exposure, highlighting a trade-off between short-term performance and long-term durability.
The pore–fracture system in coal reservoirs is a critical factor controlling coalbed methane (CBM) productivity. This study focuses on deep coal samples from the Benxi and Taiyuan formations in the southeastern margin of the Ordos Basin. Using low-pressure CO2 and N2 adsorption experiments combined with fractal theory (Song and FHH models), the pore structure and heterogeneity of micropores (<2 nm) and mesopores (2–100 nm) were systematically analyzed. The results indicate that ash content is the primary inhibiting factor for pore development, showing significant negative correlations with micropore specific surface area, pore volume, and mesopore volume. The influence of macerals exhibits scale-dependent effects: vitrinite is the main contributor to micropore development, while vitrinite and ash content show a synergistic positive correlation with the volume proportion of 10–50 nm mesopores. Thermal maturity has no significant impact on pore volume but notably enhances mesopore heterogeneity. This study reveals an “ash-dominant, vitrinite-assisted” pore development pattern in low- to medium-rank coals, providing a theoretical basis for the efficient development of deep CBM.
The irreducible water saturation of reservoirs seriously restricts the efficient drainage of unconventional energy sources. NMR logging can be used to determine parameters such as total porosity, effective porosity, irreducible water saturation, and permeability, which play an important role in oil and gas identification. T2 cut off value identification using the NMR T2 spectrum is the key to clarifying the irreducible water saturation of unconventional reservoirs. In this paper, saturation and centrifugal T2 spectra of sandstone and coal samples are used to study and calculate the T2 cut off value, with methods including single fractal dimension, multi-fractal dimension, and spectrum morphological discrimination; in addition, the applicability of these three methods in characterizing T2 cut off is discussed. According to the morphological difference of the saturated T2 spectrum, relationships between morphological parameters and the T2 cut off of four types of sample are described. The parameters related to T2 cut off can be divided into two types: (1) the first type includes morphological parameters main peak position (TM) and smaller-pore volume percentage (SPVP); with an increase of T2 cut off, TM increases linearly and SPVP decreases exponentially, and the correlation between SPVP and T2 cut off is stronger than that of TM. (2) The other type includes fractal parameters D2 (fractal dimension of larger pore), D−10 – D10, and D−10/D10; with the increase of T2 cut off, single and multi-fractal dimensions all increase linearly, and the correlation between D2 and T2 cut off is stronger than that of the multi-fractal dimension. When calculating the T2 cut off of samples with macro-pores developed, spectrum morphological methods should be used preferentially, while the fractal dimension discrimination methods need be used for the T2 cut off of samples with developed micro-pores. Then, the T2 cut off value prediction and evaluation system are described. The overall results of this work can provide a theoretical basis for the inversion of bound water content in the original formation.