We investigated the effect of film thickness d on the acoustic response of titanium dioxide (TiO₂) layers deposited on Ti, SiO₂, Al₂O₃, and Si substrates. For each TiO₂ thickness–substrate pair, we computed reflection coefficients and acoustic signatures under normal operating conditions of a conventional scanning acoustic microscope, then deduced the Rayleigh-wave velocity V_R from spectral analysis of the oscillatory layer–substrate signatures. As d increased, V_R either rose or fell, depending on the layer/substrate pair, and eventually approached a saturation value. For TiO₂/SiO₂ and TiO₂/Ti, V_R increased from those of the bare substrates (SiO₂: 3415 m/s; Ti: 2965 m/s) toward 3830 m·s⁻¹, the bulk TiO₂ value. For TiO₂/Al₂O₃ and TiO₂/Si, V_R decreased from the substrate values (Al₂O₃: 5700 m/s; Si: 4712 m/s) toward the same TiO₂ saturation. These dispersion trends are consistent with stiffening (V_R (TiO₂) > V_R (Substrate)) or loading (V_R (TiO₂) < V_R (Substrate)) effects. The resulting V_R–d dispersion charts provide theoretical reference trends relating thickness and Rayleigh-wave velocity for the idealized TiO₂/substrate systems considered here.

This study examines the functional degradation of crystalline silicon photovoltaic cells after 17 years of field exposure in the Adrar Desert, Algeria. Harsh thermal, radiative, and mechanical conditions accelerate aging, affecting electrical performance and structural stability. Monocrystalline silicon cells were extracted and analyzed by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Raman spectroscopy, electrical resistivity measurements, and vibrating sample magnetometry (VSM). SEM revealed microcracks, delamination, and corrosion products. EDS showed Ag, Si, O, and C signals, while Raman indicated silicon features and signatures consistent with encapsulant (EVA) degradation. The temperature-dependent resistivity displayed a dual behavior with a minimum near ~72 °C, above which resistivity increased, consistent with a transition in the dominant transport mechanisms. VSM measurements showed an overall diamagnetic response with a weak hysteresis loop suggestive of defect-related contributions. The observed aging is primarily associated with oxidation, metal migration, and encapsulant degradation. These findings motivate more robust materials and interfaces for desert climates, alongside improved thermal management and active monitoring.